{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2013:3L3AWUHBZLOGSHOKRYEAOBRCXM","short_pith_number":"pith:3L3AWUHB","canonical_record":{"source":{"id":"1310.5416","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-10-21T04:08:40Z","cross_cats_sorted":["cond-mat.supr-con"],"title_canon_sha256":"826d33b79bc960b34c8314f9df22ba2bfe12301af7bfaaf986966053514537f4","abstract_canon_sha256":"b51841d2750b327bf950909096e28b57c70db0a5c32dc02f8b7b6438775faa6b"},"schema_version":"1.0"},"canonical_sha256":"daf60b50e1cadc691dca8e08070622bb125b45837ca53f0c9d10ad629a88d2cf","source":{"kind":"arxiv","id":"1310.5416","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1310.5416","created_at":"2026-05-18T01:46:57Z"},{"alias_kind":"arxiv_version","alias_value":"1310.5416v2","created_at":"2026-05-18T01:46:57Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1310.5416","created_at":"2026-05-18T01:46:57Z"},{"alias_kind":"pith_short_12","alias_value":"3L3AWUHBZLOG","created_at":"2026-05-18T12:27:32Z"},{"alias_kind":"pith_short_16","alias_value":"3L3AWUHBZLOGSHOK","created_at":"2026-05-18T12:27:32Z"},{"alias_kind":"pith_short_8","alias_value":"3L3AWUHB","created_at":"2026-05-18T12:27:32Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2013:3L3AWUHBZLOGSHOKRYEAOBRCXM","target":"record","payload":{"canonical_record":{"source":{"id":"1310.5416","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-10-21T04:08:40Z","cross_cats_sorted":["cond-mat.supr-con"],"title_canon_sha256":"826d33b79bc960b34c8314f9df22ba2bfe12301af7bfaaf986966053514537f4","abstract_canon_sha256":"b51841d2750b327bf950909096e28b57c70db0a5c32dc02f8b7b6438775faa6b"},"schema_version":"1.0"},"canonical_sha256":"daf60b50e1cadc691dca8e08070622bb125b45837ca53f0c9d10ad629a88d2cf","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:46:57.252749Z","signature_b64":"2z3ZzjeKCRNsqvL2LqY+BG1Q8vZMzWuIvn1AU4Ntdt7VvFmOxjbUMGCPXRPIfFGOwDHFPOdRde1eON392zEPAg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"daf60b50e1cadc691dca8e08070622bb125b45837ca53f0c9d10ad629a88d2cf","last_reissued_at":"2026-05-18T01:46:57.251848Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:46:57.251848Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1310.5416","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:46:57Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"jCJWpKG0zpXa8xke18400VQLOhsSAy/7Yrv28//vBUslX4l3Ptj91IKZBISk1k7rTyT50r/rZLN4mbv+u4yXCg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-23T14:31:58.698956Z"},"content_sha256":"e072cbee95fd89709901d9eb10d40a544e2ee219d6f44e3027444696be0a57fb","schema_version":"1.0","event_id":"sha256:e072cbee95fd89709901d9eb10d40a544e2ee219d6f44e3027444696be0a57fb"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2013:3L3AWUHBZLOGSHOKRYEAOBRCXM","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Towards a Mechanism of Rattler Coupling in the {\\beta}-Pyrochlores AOs2O6 (A = K, Rb, Cs)","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.supr-con"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"E. Shoko, G. J. Kearley, V. K. Peterson","submitted_at":"2013-10-21T04:08:40Z","abstract_excerpt":"We have applied ab initio molecular dynamics (MD) simulations to study metal-metal coupling on the alkali-metal sublattice in the {\\beta}-pyrochlore osmates, AOs2O6 (A = K, Rb, Cs) at 300 K. We find that the alkali-metal atoms (rattlers) couple to each other more strongly than they couple to the cage atoms, and that, at 300 K, this coupling is strongest for Cs. We show that this coupling controls the dominant dynamics in the rattling of these atoms. We provide preliminary evidence that the rattlers couple to each other primarily through the T2g mode whereas their coupling to the cage modes occ"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1310.5416","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:46:57Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Xa5Xqo18tgQi16gYF4LY6Pyl4f4InVMhUarQvccAgdbjd5BXoY8vs9SYUzuvLWSrF9sdEYAaw/M11jcqOH3cDg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-23T14:31:58.699305Z"},"content_sha256":"5f4da6f90897451b8acfd530ba2d2c912a539f1292e30807f5df35ee54f6f7dd","schema_version":"1.0","event_id":"sha256:5f4da6f90897451b8acfd530ba2d2c912a539f1292e30807f5df35ee54f6f7dd"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/3L3AWUHBZLOGSHOKRYEAOBRCXM/bundle.json","state_url":"https://pith.science/pith/3L3AWUHBZLOGSHOKRYEAOBRCXM/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/3L3AWUHBZLOGSHOKRYEAOBRCXM/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-23T14:31:58Z","links":{"resolver":"https://pith.science/pith/3L3AWUHBZLOGSHOKRYEAOBRCXM","bundle":"https://pith.science/pith/3L3AWUHBZLOGSHOKRYEAOBRCXM/bundle.json","state":"https://pith.science/pith/3L3AWUHBZLOGSHOKRYEAOBRCXM/state.json","well_known_bundle":"https://pith.science/.well-known/pith/3L3AWUHBZLOGSHOKRYEAOBRCXM/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2013:3L3AWUHBZLOGSHOKRYEAOBRCXM","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"b51841d2750b327bf950909096e28b57c70db0a5c32dc02f8b7b6438775faa6b","cross_cats_sorted":["cond-mat.supr-con"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-10-21T04:08:40Z","title_canon_sha256":"826d33b79bc960b34c8314f9df22ba2bfe12301af7bfaaf986966053514537f4"},"schema_version":"1.0","source":{"id":"1310.5416","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1310.5416","created_at":"2026-05-18T01:46:57Z"},{"alias_kind":"arxiv_version","alias_value":"1310.5416v2","created_at":"2026-05-18T01:46:57Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1310.5416","created_at":"2026-05-18T01:46:57Z"},{"alias_kind":"pith_short_12","alias_value":"3L3AWUHBZLOG","created_at":"2026-05-18T12:27:32Z"},{"alias_kind":"pith_short_16","alias_value":"3L3AWUHBZLOGSHOK","created_at":"2026-05-18T12:27:32Z"},{"alias_kind":"pith_short_8","alias_value":"3L3AWUHB","created_at":"2026-05-18T12:27:32Z"}],"graph_snapshots":[{"event_id":"sha256:5f4da6f90897451b8acfd530ba2d2c912a539f1292e30807f5df35ee54f6f7dd","target":"graph","created_at":"2026-05-18T01:46:57Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We have applied ab initio molecular dynamics (MD) simulations to study metal-metal coupling on the alkali-metal sublattice in the {\\beta}-pyrochlore osmates, AOs2O6 (A = K, Rb, Cs) at 300 K. We find that the alkali-metal atoms (rattlers) couple to each other more strongly than they couple to the cage atoms, and that, at 300 K, this coupling is strongest for Cs. We show that this coupling controls the dominant dynamics in the rattling of these atoms. We provide preliminary evidence that the rattlers couple to each other primarily through the T2g mode whereas their coupling to the cage modes occ","authors_text":"E. Shoko, G. J. Kearley, V. K. Peterson","cross_cats":["cond-mat.supr-con"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-10-21T04:08:40Z","title":"Towards a Mechanism of Rattler Coupling in the {\\beta}-Pyrochlores AOs2O6 (A = K, Rb, Cs)"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1310.5416","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:e072cbee95fd89709901d9eb10d40a544e2ee219d6f44e3027444696be0a57fb","target":"record","created_at":"2026-05-18T01:46:57Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"b51841d2750b327bf950909096e28b57c70db0a5c32dc02f8b7b6438775faa6b","cross_cats_sorted":["cond-mat.supr-con"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-10-21T04:08:40Z","title_canon_sha256":"826d33b79bc960b34c8314f9df22ba2bfe12301af7bfaaf986966053514537f4"},"schema_version":"1.0","source":{"id":"1310.5416","kind":"arxiv","version":2}},"canonical_sha256":"daf60b50e1cadc691dca8e08070622bb125b45837ca53f0c9d10ad629a88d2cf","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"daf60b50e1cadc691dca8e08070622bb125b45837ca53f0c9d10ad629a88d2cf","first_computed_at":"2026-05-18T01:46:57.251848Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T01:46:57.251848Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"2z3ZzjeKCRNsqvL2LqY+BG1Q8vZMzWuIvn1AU4Ntdt7VvFmOxjbUMGCPXRPIfFGOwDHFPOdRde1eON392zEPAg==","signature_status":"signed_v1","signed_at":"2026-05-18T01:46:57.252749Z","signed_message":"canonical_sha256_bytes"},"source_id":"1310.5416","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:e072cbee95fd89709901d9eb10d40a544e2ee219d6f44e3027444696be0a57fb","sha256:5f4da6f90897451b8acfd530ba2d2c912a539f1292e30807f5df35ee54f6f7dd"],"state_sha256":"8913a4321533c1665c4c5cfbaa3c5dd6ffaae2cb8159e6228c23adc84890b8c2"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"RBoCEiBR5jDS1UIWnKMSYEX5+tbHXHB9tXOIpZLIUIzAOWa3ob4UT/77ey2RXbSaev3VfZqFwxtvVBL10mb2DQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-23T14:31:58.701173Z","bundle_sha256":"d63231aab911e07abf3ef362dace1f4f7c07648f05fa59913086e7411a71fe96"}}