{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2015:7JPOTCOX7BT7IC5U47XSN6MDDI","short_pith_number":"pith:7JPOTCOX","canonical_record":{"source":{"id":"1502.03533","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2015-02-12T04:11:17Z","cross_cats_sorted":[],"title_canon_sha256":"ae6166a398218cbf63def2fa767eba4a4fd14c3ff8f0f188e1c654020bb0589c","abstract_canon_sha256":"be7f6cd51970559c83c4cd3d4f51bbd32c02b0edba72394febe9ddd0884c47fe"},"schema_version":"1.0"},"canonical_sha256":"fa5ee989d7f867f40bb4e7ef26f9831a0f0dfe7664f7bc9e919bf2d88fdb56cf","source":{"kind":"arxiv","id":"1502.03533","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1502.03533","created_at":"2026-05-18T01:21:19Z"},{"alias_kind":"arxiv_version","alias_value":"1502.03533v1","created_at":"2026-05-18T01:21:19Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1502.03533","created_at":"2026-05-18T01:21:19Z"},{"alias_kind":"pith_short_12","alias_value":"7JPOTCOX7BT7","created_at":"2026-05-18T12:29:10Z"},{"alias_kind":"pith_short_16","alias_value":"7JPOTCOX7BT7IC5U","created_at":"2026-05-18T12:29:10Z"},{"alias_kind":"pith_short_8","alias_value":"7JPOTCOX","created_at":"2026-05-18T12:29:10Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2015:7JPOTCOX7BT7IC5U47XSN6MDDI","target":"record","payload":{"canonical_record":{"source":{"id":"1502.03533","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2015-02-12T04:11:17Z","cross_cats_sorted":[],"title_canon_sha256":"ae6166a398218cbf63def2fa767eba4a4fd14c3ff8f0f188e1c654020bb0589c","abstract_canon_sha256":"be7f6cd51970559c83c4cd3d4f51bbd32c02b0edba72394febe9ddd0884c47fe"},"schema_version":"1.0"},"canonical_sha256":"fa5ee989d7f867f40bb4e7ef26f9831a0f0dfe7664f7bc9e919bf2d88fdb56cf","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:21:19.684463Z","signature_b64":"xS7TdrWuKgmSNU1t8drHlRqxzK+z9zslySJ/Q5LpapNgVAxDPe5bSi09X+0T4pFQPeoNRhOouJqDdFnVxCClCg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"fa5ee989d7f867f40bb4e7ef26f9831a0f0dfe7664f7bc9e919bf2d88fdb56cf","last_reissued_at":"2026-05-18T01:21:19.683812Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:21:19.683812Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1502.03533","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:21:19Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"7mxKSISpIw/I9P+tqm7t6A3vHblrIFgzJR/CeksrUHj4H0Nvns2pYkJA1Z9oe3KLidvi3n+IYcKxWDJvQ5vwCA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-19T22:28:43.644722Z"},"content_sha256":"19430739989b3d9ecbf9393c988a5a4cf17b1291590b617327d4f1d0ad2c45c8","schema_version":"1.0","event_id":"sha256:19430739989b3d9ecbf9393c988a5a4cf17b1291590b617327d4f1d0ad2c45c8"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2015:7JPOTCOX7BT7IC5U47XSN6MDDI","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Lithium and sodium storage on tetracyanoethylene (TCNE) and TCNE-(doped)-graphene complexes: a computational study","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Sergei Manzhos, Yingqian Chen","submitted_at":"2015-02-12T04:11:17Z","abstract_excerpt":"Li and Na attachment to free tetracyanoethylene (TCNE) molecules and TCNE adsorbed on doped graphene is studied using density functional theory. While TCNE is adsorbed only weakly on ideal graphene, we identified a configuration in which TCNE is chemisorbed on Al-doped graphene via molecule C atom and a surface oxygen atom. Up to four (five) Li and Na atoms can be stored on both free (adsorbed) TCNE with binding energies stronger than cohesive energies of the Li and Na metals. When storing up to three atoms per molecule, it should be possible to avoid reduction of common battery electrolytes. "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1502.03533","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:21:19Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"cgmTPW6KN3JKuifyeRIuS1lH8XjUVxk55ncnAOeSIOwsQVQC4DELTTg78GWoZD1vKQoSTIePSWCw1u5Bv6F4Ag==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-19T22:28:43.645045Z"},"content_sha256":"2961f993424a38093f7aa7e8d1958733b5f6180cc6e9eb9f440b4d88a29d9345","schema_version":"1.0","event_id":"sha256:2961f993424a38093f7aa7e8d1958733b5f6180cc6e9eb9f440b4d88a29d9345"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/7JPOTCOX7BT7IC5U47XSN6MDDI/bundle.json","state_url":"https://pith.science/pith/7JPOTCOX7BT7IC5U47XSN6MDDI/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/7JPOTCOX7BT7IC5U47XSN6MDDI/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-19T22:28:43Z","links":{"resolver":"https://pith.science/pith/7JPOTCOX7BT7IC5U47XSN6MDDI","bundle":"https://pith.science/pith/7JPOTCOX7BT7IC5U47XSN6MDDI/bundle.json","state":"https://pith.science/pith/7JPOTCOX7BT7IC5U47XSN6MDDI/state.json","well_known_bundle":"https://pith.science/.well-known/pith/7JPOTCOX7BT7IC5U47XSN6MDDI/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2015:7JPOTCOX7BT7IC5U47XSN6MDDI","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"be7f6cd51970559c83c4cd3d4f51bbd32c02b0edba72394febe9ddd0884c47fe","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2015-02-12T04:11:17Z","title_canon_sha256":"ae6166a398218cbf63def2fa767eba4a4fd14c3ff8f0f188e1c654020bb0589c"},"schema_version":"1.0","source":{"id":"1502.03533","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1502.03533","created_at":"2026-05-18T01:21:19Z"},{"alias_kind":"arxiv_version","alias_value":"1502.03533v1","created_at":"2026-05-18T01:21:19Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1502.03533","created_at":"2026-05-18T01:21:19Z"},{"alias_kind":"pith_short_12","alias_value":"7JPOTCOX7BT7","created_at":"2026-05-18T12:29:10Z"},{"alias_kind":"pith_short_16","alias_value":"7JPOTCOX7BT7IC5U","created_at":"2026-05-18T12:29:10Z"},{"alias_kind":"pith_short_8","alias_value":"7JPOTCOX","created_at":"2026-05-18T12:29:10Z"}],"graph_snapshots":[{"event_id":"sha256:2961f993424a38093f7aa7e8d1958733b5f6180cc6e9eb9f440b4d88a29d9345","target":"graph","created_at":"2026-05-18T01:21:19Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Li and Na attachment to free tetracyanoethylene (TCNE) molecules and TCNE adsorbed on doped graphene is studied using density functional theory. While TCNE is adsorbed only weakly on ideal graphene, we identified a configuration in which TCNE is chemisorbed on Al-doped graphene via molecule C atom and a surface oxygen atom. Up to four (five) Li and Na atoms can be stored on both free (adsorbed) TCNE with binding energies stronger than cohesive energies of the Li and Na metals. When storing up to three atoms per molecule, it should be possible to avoid reduction of common battery electrolytes. ","authors_text":"Sergei Manzhos, Yingqian Chen","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2015-02-12T04:11:17Z","title":"Lithium and sodium storage on tetracyanoethylene (TCNE) and TCNE-(doped)-graphene complexes: a computational study"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1502.03533","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:19430739989b3d9ecbf9393c988a5a4cf17b1291590b617327d4f1d0ad2c45c8","target":"record","created_at":"2026-05-18T01:21:19Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"be7f6cd51970559c83c4cd3d4f51bbd32c02b0edba72394febe9ddd0884c47fe","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2015-02-12T04:11:17Z","title_canon_sha256":"ae6166a398218cbf63def2fa767eba4a4fd14c3ff8f0f188e1c654020bb0589c"},"schema_version":"1.0","source":{"id":"1502.03533","kind":"arxiv","version":1}},"canonical_sha256":"fa5ee989d7f867f40bb4e7ef26f9831a0f0dfe7664f7bc9e919bf2d88fdb56cf","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"fa5ee989d7f867f40bb4e7ef26f9831a0f0dfe7664f7bc9e919bf2d88fdb56cf","first_computed_at":"2026-05-18T01:21:19.683812Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T01:21:19.683812Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"xS7TdrWuKgmSNU1t8drHlRqxzK+z9zslySJ/Q5LpapNgVAxDPe5bSi09X+0T4pFQPeoNRhOouJqDdFnVxCClCg==","signature_status":"signed_v1","signed_at":"2026-05-18T01:21:19.684463Z","signed_message":"canonical_sha256_bytes"},"source_id":"1502.03533","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:19430739989b3d9ecbf9393c988a5a4cf17b1291590b617327d4f1d0ad2c45c8","sha256:2961f993424a38093f7aa7e8d1958733b5f6180cc6e9eb9f440b4d88a29d9345"],"state_sha256":"b600cf379bd97fc0390ee4f4f7a1dfca46de52b5cc854c9d38e67bf7162807ee"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"NiyQ14k5H1CagMc0JsHhh6fZVZo3LRbD3FiHf4xs+VgVOLTWwbFXSBrY5UlFZiXNUK1zWbVXUD03FmBS+6RYBg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-19T22:28:43.646868Z","bundle_sha256":"c4d5019f6e5fb320553ee8d5a4e849b0a9e3e55f9e7313023af9648798de71e4"}}