{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2017:FPPZ64GR6O3UKKCTZ3L6TKU6FZ","short_pith_number":"pith:FPPZ64GR","canonical_record":{"source":{"id":"1710.06343","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.GA","submitted_at":"2017-10-17T15:25:05Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"b6b63e3ff8f84b5e758e12576749f56ad703132aef23d2831b77580017edeebe","abstract_canon_sha256":"790d43d07ba3c1b4859fc9aa2f5a1a10a95831903b5b88677d560a01a768efae"},"schema_version":"1.0"},"canonical_sha256":"2bdf9f70d1f3b7452853ced7e9aa9e2e4792401b836a1ddd175d055da0f15ede","source":{"kind":"arxiv","id":"1710.06343","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1710.06343","created_at":"2026-05-18T00:32:33Z"},{"alias_kind":"arxiv_version","alias_value":"1710.06343v1","created_at":"2026-05-18T00:32:33Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1710.06343","created_at":"2026-05-18T00:32:33Z"},{"alias_kind":"pith_short_12","alias_value":"FPPZ64GR6O3U","created_at":"2026-05-18T12:31:15Z"},{"alias_kind":"pith_short_16","alias_value":"FPPZ64GR6O3UKKCT","created_at":"2026-05-18T12:31:15Z"},{"alias_kind":"pith_short_8","alias_value":"FPPZ64GR","created_at":"2026-05-18T12:31:15Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2017:FPPZ64GR6O3UKKCTZ3L6TKU6FZ","target":"record","payload":{"canonical_record":{"source":{"id":"1710.06343","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.GA","submitted_at":"2017-10-17T15:25:05Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"b6b63e3ff8f84b5e758e12576749f56ad703132aef23d2831b77580017edeebe","abstract_canon_sha256":"790d43d07ba3c1b4859fc9aa2f5a1a10a95831903b5b88677d560a01a768efae"},"schema_version":"1.0"},"canonical_sha256":"2bdf9f70d1f3b7452853ced7e9aa9e2e4792401b836a1ddd175d055da0f15ede","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:32:33.643585Z","signature_b64":"Mabq8IyO7AEf8fUYdHXpHLi9GmrvNjeDeQvdpIJ8k+KZJzCdWAUpYpOos4eOqsHtzJA7LObxTFy4ylNuXXgzDw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"2bdf9f70d1f3b7452853ced7e9aa9e2e4792401b836a1ddd175d055da0f15ede","last_reissued_at":"2026-05-18T00:32:33.642971Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:32:33.642971Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1710.06343","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:32:33Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"AqC7iMIJvxc0Cso0jyYT1P3O+7wnoNam6ESHjYvYdH/nC/RaFBnQvcsUx/F5cBmuYzn3HeZSmaA2T6KIHI95Bg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-25T22:56:42.577412Z"},"content_sha256":"8a5a1045a2c6e6936136d5fef4b8ba81b8f87b7370ea8361693b4782f9b0d526","schema_version":"1.0","event_id":"sha256:8a5a1045a2c6e6936136d5fef4b8ba81b8f87b7370ea8361693b4782f9b0d526"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2017:FPPZ64GR6O3UKKCTZ3L6TKU6FZ","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Associative detachment (AD) paths for H and CN- in the gas-phase: astrophysical implications","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"astro-ph.GA","authors_text":"Franco A. Gianturco, Roland Wester, Stanka V. Jerosimic","submitted_at":"2017-10-17T15:25:05Z","abstract_excerpt":"The direct dynamical paths leading to Associative Detachment (AD) in the gas-phase, and specifically in the low-temperature regions of the Dark Molecular Clouds (DMC) in the ISM, or in cold trap laboratory experiments, are investigated with quantum chemical methods by using a high-level multi-reference Configuration Interaction (CI) approach that employs single and double excitations plus Davidson perturbative correction [MRSDCI(Q)] and the d-aug-cc-pV5Z basis set. The potential energy curves for H + CN- are constructed for different directions of the H partner approaching the CN- anion within"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1710.06343","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:32:33Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"GrQCIBXE921x39o1vpuDXKa57ZOpwYFAWjt5bZmOjUaPswcWatgn/THMzgfXTHA3tLzeJYBg9V2Ot1DgGGxfDw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-25T22:56:42.577766Z"},"content_sha256":"582507b9c8e9c3fea865d7f4f93ec7310075473927264c69a4b93828c99a00c9","schema_version":"1.0","event_id":"sha256:582507b9c8e9c3fea865d7f4f93ec7310075473927264c69a4b93828c99a00c9"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/FPPZ64GR6O3UKKCTZ3L6TKU6FZ/bundle.json","state_url":"https://pith.science/pith/FPPZ64GR6O3UKKCTZ3L6TKU6FZ/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/FPPZ64GR6O3UKKCTZ3L6TKU6FZ/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-25T22:56:42Z","links":{"resolver":"https://pith.science/pith/FPPZ64GR6O3UKKCTZ3L6TKU6FZ","bundle":"https://pith.science/pith/FPPZ64GR6O3UKKCTZ3L6TKU6FZ/bundle.json","state":"https://pith.science/pith/FPPZ64GR6O3UKKCTZ3L6TKU6FZ/state.json","well_known_bundle":"https://pith.science/.well-known/pith/FPPZ64GR6O3UKKCTZ3L6TKU6FZ/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2017:FPPZ64GR6O3UKKCTZ3L6TKU6FZ","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"790d43d07ba3c1b4859fc9aa2f5a1a10a95831903b5b88677d560a01a768efae","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.GA","submitted_at":"2017-10-17T15:25:05Z","title_canon_sha256":"b6b63e3ff8f84b5e758e12576749f56ad703132aef23d2831b77580017edeebe"},"schema_version":"1.0","source":{"id":"1710.06343","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1710.06343","created_at":"2026-05-18T00:32:33Z"},{"alias_kind":"arxiv_version","alias_value":"1710.06343v1","created_at":"2026-05-18T00:32:33Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1710.06343","created_at":"2026-05-18T00:32:33Z"},{"alias_kind":"pith_short_12","alias_value":"FPPZ64GR6O3U","created_at":"2026-05-18T12:31:15Z"},{"alias_kind":"pith_short_16","alias_value":"FPPZ64GR6O3UKKCT","created_at":"2026-05-18T12:31:15Z"},{"alias_kind":"pith_short_8","alias_value":"FPPZ64GR","created_at":"2026-05-18T12:31:15Z"}],"graph_snapshots":[{"event_id":"sha256:582507b9c8e9c3fea865d7f4f93ec7310075473927264c69a4b93828c99a00c9","target":"graph","created_at":"2026-05-18T00:32:33Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"The direct dynamical paths leading to Associative Detachment (AD) in the gas-phase, and specifically in the low-temperature regions of the Dark Molecular Clouds (DMC) in the ISM, or in cold trap laboratory experiments, are investigated with quantum chemical methods by using a high-level multi-reference Configuration Interaction (CI) approach that employs single and double excitations plus Davidson perturbative correction [MRSDCI(Q)] and the d-aug-cc-pV5Z basis set. The potential energy curves for H + CN- are constructed for different directions of the H partner approaching the CN- anion within","authors_text":"Franco A. Gianturco, Roland Wester, Stanka V. Jerosimic","cross_cats":["physics.chem-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.GA","submitted_at":"2017-10-17T15:25:05Z","title":"Associative detachment (AD) paths for H and CN- in the gas-phase: astrophysical implications"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1710.06343","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:8a5a1045a2c6e6936136d5fef4b8ba81b8f87b7370ea8361693b4782f9b0d526","target":"record","created_at":"2026-05-18T00:32:33Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"790d43d07ba3c1b4859fc9aa2f5a1a10a95831903b5b88677d560a01a768efae","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.GA","submitted_at":"2017-10-17T15:25:05Z","title_canon_sha256":"b6b63e3ff8f84b5e758e12576749f56ad703132aef23d2831b77580017edeebe"},"schema_version":"1.0","source":{"id":"1710.06343","kind":"arxiv","version":1}},"canonical_sha256":"2bdf9f70d1f3b7452853ced7e9aa9e2e4792401b836a1ddd175d055da0f15ede","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"2bdf9f70d1f3b7452853ced7e9aa9e2e4792401b836a1ddd175d055da0f15ede","first_computed_at":"2026-05-18T00:32:33.642971Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:32:33.642971Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"Mabq8IyO7AEf8fUYdHXpHLi9GmrvNjeDeQvdpIJ8k+KZJzCdWAUpYpOos4eOqsHtzJA7LObxTFy4ylNuXXgzDw==","signature_status":"signed_v1","signed_at":"2026-05-18T00:32:33.643585Z","signed_message":"canonical_sha256_bytes"},"source_id":"1710.06343","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:8a5a1045a2c6e6936136d5fef4b8ba81b8f87b7370ea8361693b4782f9b0d526","sha256:582507b9c8e9c3fea865d7f4f93ec7310075473927264c69a4b93828c99a00c9"],"state_sha256":"143c44731d539d5f3c16ff1040e2b1d5376ba9f7e343365a69fcb10414aba714"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"uXzHJ7y0CJ1uox9VSYhoZPm14Mq1FXWLt0wV/Hm1ORKegsmb3OpkTnkJPadNk4rTD6Kc6Co/CClfXBMtAy+3Bw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-25T22:56:42.579763Z","bundle_sha256":"85a8d5639b3cb0aeb87cb8c5090b2f2975fbdf3cbc1a18874db29b55836b88f1"}}