{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2014:G4AZXOUCZ3LESRI3QHGHZQE3KB","short_pith_number":"pith:G4AZXOUC","canonical_record":{"source":{"id":"1407.1409","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2014-07-05T14:17:35Z","cross_cats_sorted":[],"title_canon_sha256":"95d0d238ac9bf659b194e6e7b4f7d9da0c07ed402d652942e3ad9502ddd73941","abstract_canon_sha256":"435dfe9fe55b9c50bb236e8a3bfba3b533abb6cea8759d5ef63a1530c94bcd98"},"schema_version":"1.0"},"canonical_sha256":"37019bba82ced649451b81cc7cc09b5071746d8b710191001f017fc9c4a9e744","source":{"kind":"arxiv","id":"1407.1409","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1407.1409","created_at":"2026-05-18T02:48:16Z"},{"alias_kind":"arxiv_version","alias_value":"1407.1409v1","created_at":"2026-05-18T02:48:16Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1407.1409","created_at":"2026-05-18T02:48:16Z"},{"alias_kind":"pith_short_12","alias_value":"G4AZXOUCZ3LE","created_at":"2026-05-18T12:28:28Z"},{"alias_kind":"pith_short_16","alias_value":"G4AZXOUCZ3LESRI3","created_at":"2026-05-18T12:28:28Z"},{"alias_kind":"pith_short_8","alias_value":"G4AZXOUC","created_at":"2026-05-18T12:28:28Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2014:G4AZXOUCZ3LESRI3QHGHZQE3KB","target":"record","payload":{"canonical_record":{"source":{"id":"1407.1409","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2014-07-05T14:17:35Z","cross_cats_sorted":[],"title_canon_sha256":"95d0d238ac9bf659b194e6e7b4f7d9da0c07ed402d652942e3ad9502ddd73941","abstract_canon_sha256":"435dfe9fe55b9c50bb236e8a3bfba3b533abb6cea8759d5ef63a1530c94bcd98"},"schema_version":"1.0"},"canonical_sha256":"37019bba82ced649451b81cc7cc09b5071746d8b710191001f017fc9c4a9e744","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T02:48:16.646069Z","signature_b64":"UyNP8dMZvw5Cg0ZK7Wb8qOJjqQtNqmJ0cEeAmB5AXcQDcwj+c+0b//O5QiFzp60YPoVfYiG4kl9wV03A1F+EDQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"37019bba82ced649451b81cc7cc09b5071746d8b710191001f017fc9c4a9e744","last_reissued_at":"2026-05-18T02:48:16.645692Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T02:48:16.645692Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1407.1409","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T02:48:16Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"uo1tQLyQ0PtTPUbQPebk6YVuYpBgX95r/Nq+IY3j+l/WoxKKkOrfxkcDAd4rKUESFvnqRorzIqACxOBMA+aLBw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-01T14:39:54.726918Z"},"content_sha256":"a385c379613ec7a3a6f92655224e9d1ed26d119bb3d81e347b3402550a439feb","schema_version":"1.0","event_id":"sha256:a385c379613ec7a3a6f92655224e9d1ed26d119bb3d81e347b3402550a439feb"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2014:G4AZXOUCZ3LESRI3QHGHZQE3KB","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Anomalous multi-order Raman scattering in LaMnO_3: a signature of a quantum lattice effect in a Jahn-Teller crystal","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.str-el","authors_text":"A. A. Maksimov, A. Dejneka, A. M. Balbashov, A. M. Stoneham, D. Nuzhnyy, E. I. Demikhov, F. V. Kusmartsev, K. I. Kugel, N. N. Kovaleva, O. E. Kusmartseva, V. A. Trepakov","submitted_at":"2014-07-05T14:17:35Z","abstract_excerpt":"The multi-order Raman scattering is studied up to a fourth order for a detwinned LaMnO_3 crystal. Based on a comprehensive data analysis of the polarisation-dependent Raman spectra, we show that the anomalous features in the multi-order scattering could be the sidebands on the low-energy mode at about 25 cm-1. We suggest that this low-energy mode stems from the tunneling transition between the potential energy minima arising near the Jahn-Teller Mn3+ ion due to the lattice anharmonicity, and the multi-order scattering is activated by this low-energy electronic motion. The sidebands are dominat"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1407.1409","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T02:48:16Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"zEeQYSNWdLNDrSqAQGpB0rQeyYLwX/V2w7iXI6Ns8IjErU45YviNyfkPmPNgT1liVZLhkBQTp9ngqUNAJkuWBw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-01T14:39:54.727264Z"},"content_sha256":"67c03efad5d3f3f7df2e552afcd84f77a40fb60b968cdc63adb8416e7e53c010","schema_version":"1.0","event_id":"sha256:67c03efad5d3f3f7df2e552afcd84f77a40fb60b968cdc63adb8416e7e53c010"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/G4AZXOUCZ3LESRI3QHGHZQE3KB/bundle.json","state_url":"https://pith.science/pith/G4AZXOUCZ3LESRI3QHGHZQE3KB/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/G4AZXOUCZ3LESRI3QHGHZQE3KB/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-01T14:39:54Z","links":{"resolver":"https://pith.science/pith/G4AZXOUCZ3LESRI3QHGHZQE3KB","bundle":"https://pith.science/pith/G4AZXOUCZ3LESRI3QHGHZQE3KB/bundle.json","state":"https://pith.science/pith/G4AZXOUCZ3LESRI3QHGHZQE3KB/state.json","well_known_bundle":"https://pith.science/.well-known/pith/G4AZXOUCZ3LESRI3QHGHZQE3KB/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2014:G4AZXOUCZ3LESRI3QHGHZQE3KB","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"435dfe9fe55b9c50bb236e8a3bfba3b533abb6cea8759d5ef63a1530c94bcd98","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2014-07-05T14:17:35Z","title_canon_sha256":"95d0d238ac9bf659b194e6e7b4f7d9da0c07ed402d652942e3ad9502ddd73941"},"schema_version":"1.0","source":{"id":"1407.1409","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1407.1409","created_at":"2026-05-18T02:48:16Z"},{"alias_kind":"arxiv_version","alias_value":"1407.1409v1","created_at":"2026-05-18T02:48:16Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1407.1409","created_at":"2026-05-18T02:48:16Z"},{"alias_kind":"pith_short_12","alias_value":"G4AZXOUCZ3LE","created_at":"2026-05-18T12:28:28Z"},{"alias_kind":"pith_short_16","alias_value":"G4AZXOUCZ3LESRI3","created_at":"2026-05-18T12:28:28Z"},{"alias_kind":"pith_short_8","alias_value":"G4AZXOUC","created_at":"2026-05-18T12:28:28Z"}],"graph_snapshots":[{"event_id":"sha256:67c03efad5d3f3f7df2e552afcd84f77a40fb60b968cdc63adb8416e7e53c010","target":"graph","created_at":"2026-05-18T02:48:16Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"The multi-order Raman scattering is studied up to a fourth order for a detwinned LaMnO_3 crystal. Based on a comprehensive data analysis of the polarisation-dependent Raman spectra, we show that the anomalous features in the multi-order scattering could be the sidebands on the low-energy mode at about 25 cm-1. We suggest that this low-energy mode stems from the tunneling transition between the potential energy minima arising near the Jahn-Teller Mn3+ ion due to the lattice anharmonicity, and the multi-order scattering is activated by this low-energy electronic motion. The sidebands are dominat","authors_text":"A. A. Maksimov, A. Dejneka, A. M. Balbashov, A. M. Stoneham, D. Nuzhnyy, E. I. Demikhov, F. V. Kusmartsev, K. I. Kugel, N. N. Kovaleva, O. E. Kusmartseva, V. A. Trepakov","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2014-07-05T14:17:35Z","title":"Anomalous multi-order Raman scattering in LaMnO_3: a signature of a quantum lattice effect in a Jahn-Teller crystal"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1407.1409","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:a385c379613ec7a3a6f92655224e9d1ed26d119bb3d81e347b3402550a439feb","target":"record","created_at":"2026-05-18T02:48:16Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"435dfe9fe55b9c50bb236e8a3bfba3b533abb6cea8759d5ef63a1530c94bcd98","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2014-07-05T14:17:35Z","title_canon_sha256":"95d0d238ac9bf659b194e6e7b4f7d9da0c07ed402d652942e3ad9502ddd73941"},"schema_version":"1.0","source":{"id":"1407.1409","kind":"arxiv","version":1}},"canonical_sha256":"37019bba82ced649451b81cc7cc09b5071746d8b710191001f017fc9c4a9e744","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"37019bba82ced649451b81cc7cc09b5071746d8b710191001f017fc9c4a9e744","first_computed_at":"2026-05-18T02:48:16.645692Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T02:48:16.645692Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"UyNP8dMZvw5Cg0ZK7Wb8qOJjqQtNqmJ0cEeAmB5AXcQDcwj+c+0b//O5QiFzp60YPoVfYiG4kl9wV03A1F+EDQ==","signature_status":"signed_v1","signed_at":"2026-05-18T02:48:16.646069Z","signed_message":"canonical_sha256_bytes"},"source_id":"1407.1409","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:a385c379613ec7a3a6f92655224e9d1ed26d119bb3d81e347b3402550a439feb","sha256:67c03efad5d3f3f7df2e552afcd84f77a40fb60b968cdc63adb8416e7e53c010"],"state_sha256":"da45605038e7ed320ce76e3d0727177792ac15643c273c59390be7997ad52935"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"RWKyBVF7L7KF4cjjGV5Bw3cAL3np4hUCmb70nI1YoVzCVgb+obgSzcdBXCWPLhuxgrqFeF5qru1tWMwCOOsKAg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-01T14:39:54.729377Z","bundle_sha256":"ec194cca109c69f809d7491ecc9b1a3552cb7a8db38ceca79720bc2bb3f940aa"}}