{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2018:MDHZOUX3V32JRX5G7MWE4DICWS","short_pith_number":"pith:MDHZOUX3","schema_version":"1.0","canonical_sha256":"60cf9752fbaef498dfa6fb2c4e0d02b4905b26bf4f4c835bd0ea5045053eb122","source":{"kind":"arxiv","id":"1810.09314","version":1},"attestation_state":"computed","paper":{"title":"A new spectroscopically-determined potential energy surface and \\emph{ab initio} dipole moment surface for high accuracy HCN intensity calculations","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Aleksandra A. Kyuberis, Irina I. Mizus, Jonathan Tennyson, Nikolai F. Zobov, Oleg L. Polyansky, Vladimir Yu. Makhnev","submitted_at":"2018-10-22T14:25:40Z","abstract_excerpt":"Calculations of transition intensities for small molecules like H$_2$O, CO, CO$_2$ based on s high-quality potential energy surface (PES) and dipole moment surface (DMS) can nowadays reach sub-percent accuracy. An extension of this treatment to a system with more complicated internal structure -- HCN/HNC (hydrogen cyanide/hydrogen isocyanide) is presented. A highly accurate spectroscopically-determined PES is built based on a recent \\aipes\\ of the HCN/HNC isomerizing system. 588 levels of HCN with $J$~=~(0,~2,~5,~9,~10) are reproduced with a standard deviation from the experimental values of $"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1810.09314","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2018-10-22T14:25:40Z","cross_cats_sorted":[],"title_canon_sha256":"90772e20cded56f79efd18262fca05bec07ee785379215440c1b5b2a8a14bd9f","abstract_canon_sha256":"d0b55a65305c13c0b4f446e135347116cd012e65b08c67e556acd570f1278565"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:02:40.486718Z","signature_b64":"35kizZmLK8jra47xXzISJJdkyTgJlKFORVxwQQ3MNavmGb75FheyGADS5x1bznTxTMWRSmj0ishFkeGIzNUwCQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"60cf9752fbaef498dfa6fb2c4e0d02b4905b26bf4f4c835bd0ea5045053eb122","last_reissued_at":"2026-05-18T00:02:40.486198Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:02:40.486198Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"A new spectroscopically-determined potential energy surface and \\emph{ab initio} dipole moment surface for high accuracy HCN intensity calculations","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Aleksandra A. Kyuberis, Irina I. Mizus, Jonathan Tennyson, Nikolai F. Zobov, Oleg L. Polyansky, Vladimir Yu. Makhnev","submitted_at":"2018-10-22T14:25:40Z","abstract_excerpt":"Calculations of transition intensities for small molecules like H$_2$O, CO, CO$_2$ based on s high-quality potential energy surface (PES) and dipole moment surface (DMS) can nowadays reach sub-percent accuracy. An extension of this treatment to a system with more complicated internal structure -- HCN/HNC (hydrogen cyanide/hydrogen isocyanide) is presented. A highly accurate spectroscopically-determined PES is built based on a recent \\aipes\\ of the HCN/HNC isomerizing system. 588 levels of HCN with $J$~=~(0,~2,~5,~9,~10) are reproduced with a standard deviation from the experimental values of $"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1810.09314","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1810.09314","created_at":"2026-05-18T00:02:40.486278+00:00"},{"alias_kind":"arxiv_version","alias_value":"1810.09314v1","created_at":"2026-05-18T00:02:40.486278+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1810.09314","created_at":"2026-05-18T00:02:40.486278+00:00"},{"alias_kind":"pith_short_12","alias_value":"MDHZOUX3V32J","created_at":"2026-05-18T12:32:37.024351+00:00"},{"alias_kind":"pith_short_16","alias_value":"MDHZOUX3V32JRX5G","created_at":"2026-05-18T12:32:37.024351+00:00"},{"alias_kind":"pith_short_8","alias_value":"MDHZOUX3","created_at":"2026-05-18T12:32:37.024351+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/MDHZOUX3V32JRX5G7MWE4DICWS","json":"https://pith.science/pith/MDHZOUX3V32JRX5G7MWE4DICWS.json","graph_json":"https://pith.science/api/pith-number/MDHZOUX3V32JRX5G7MWE4DICWS/graph.json","events_json":"https://pith.science/api/pith-number/MDHZOUX3V32JRX5G7MWE4DICWS/events.json","paper":"https://pith.science/paper/MDHZOUX3"},"agent_actions":{"view_html":"https://pith.science/pith/MDHZOUX3V32JRX5G7MWE4DICWS","download_json":"https://pith.science/pith/MDHZOUX3V32JRX5G7MWE4DICWS.json","view_paper":"https://pith.science/paper/MDHZOUX3","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1810.09314&json=true","fetch_graph":"https://pith.science/api/pith-number/MDHZOUX3V32JRX5G7MWE4DICWS/graph.json","fetch_events":"https://pith.science/api/pith-number/MDHZOUX3V32JRX5G7MWE4DICWS/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/MDHZOUX3V32JRX5G7MWE4DICWS/action/timestamp_anchor","attest_storage":"https://pith.science/pith/MDHZOUX3V32JRX5G7MWE4DICWS/action/storage_attestation","attest_author":"https://pith.science/pith/MDHZOUX3V32JRX5G7MWE4DICWS/action/author_attestation","sign_citation":"https://pith.science/pith/MDHZOUX3V32JRX5G7MWE4DICWS/action/citation_signature","submit_replication":"https://pith.science/pith/MDHZOUX3V32JRX5G7MWE4DICWS/action/replication_record"}},"created_at":"2026-05-18T00:02:40.486278+00:00","updated_at":"2026-05-18T00:02:40.486278+00:00"}