{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2006:MMDDOSBVUTUBAMA733CC76WL7P","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"063397349db0983bb7f8fc9488ff248fe8bfd46128ebc5f020d4587df8fa484b","cross_cats_sorted":[],"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-03-08T00:42:10Z","title_canon_sha256":"5c8d4c49d1551bcfb70f3ffbd88afc60c7c9d4d74bac6f4658e7f1f1cda8a929"},"schema_version":"1.0","source":{"id":"cond-mat/0603187","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"cond-mat/0603187","created_at":"2026-05-18T01:39:48Z"},{"alias_kind":"arxiv_version","alias_value":"cond-mat/0603187v1","created_at":"2026-05-18T01:39:48Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.cond-mat/0603187","created_at":"2026-05-18T01:39:48Z"},{"alias_kind":"pith_short_12","alias_value":"MMDDOSBVUTUB","created_at":"2026-05-18T12:25:54Z"},{"alias_kind":"pith_short_16","alias_value":"MMDDOSBVUTUBAMA7","created_at":"2026-05-18T12:25:54Z"},{"alias_kind":"pith_short_8","alias_value":"MMDDOSBV","created_at":"2026-05-18T12:25:54Z"}],"graph_snapshots":[{"event_id":"sha256:086a0b7c2f860554bba83e04dee564df35153d98899bb6ddfb46f86ccf0646ff","target":"graph","created_at":"2026-05-18T01:39:48Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Two conformations of isolated single TBrPP-Co molecules on a Cu(111) surface are switched by applying +2.2 V voltage pulses from a scanning tunneling microscope tip at 4.6 K. The TBrPP-Co has a spin-active cobalt atom caged at its center and the interaction between the spin of this cobalt atom and free electrons from the Cu(111) substrate can cause a Kondo resonance. Tunneling spectroscopy data reveal that switching from the saddle to a planar molecular conformation enhances spin-electron coupling, which increases the associated Kondo temperature from 130 K to 170 K. This result demonstrates t","authors_text":"Aparna Deshpande, Saw -Wai Hla, Violeta Iancu","cross_cats":[],"headline":"","license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-03-08T00:42:10Z","title":"Manipulating Kondo Temperature via Single Molecule Switching"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"cond-mat/0603187","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:9480a704f46d80420ec32095851582328b9929df3e439900ba62b881d17f379a","target":"record","created_at":"2026-05-18T01:39:48Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"063397349db0983bb7f8fc9488ff248fe8bfd46128ebc5f020d4587df8fa484b","cross_cats_sorted":[],"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-03-08T00:42:10Z","title_canon_sha256":"5c8d4c49d1551bcfb70f3ffbd88afc60c7c9d4d74bac6f4658e7f1f1cda8a929"},"schema_version":"1.0","source":{"id":"cond-mat/0603187","kind":"arxiv","version":1}},"canonical_sha256":"6306374835a4e810301fdec42ffacbfbe03fa6ef70a982e9fea93d21e6b1ca1a","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"6306374835a4e810301fdec42ffacbfbe03fa6ef70a982e9fea93d21e6b1ca1a","first_computed_at":"2026-05-18T01:39:48.528659Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T01:39:48.528659Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"RIlPRGIGtafFlGkBhWCjm52PhPN4h4y+vR4I342KX6Psj+NTcT5lSZONZBL+9LeT2J5DjVxk0rdVXamPOU5XBw==","signature_status":"signed_v1","signed_at":"2026-05-18T01:39:48.529587Z","signed_message":"canonical_sha256_bytes"},"source_id":"cond-mat/0603187","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:9480a704f46d80420ec32095851582328b9929df3e439900ba62b881d17f379a","sha256:086a0b7c2f860554bba83e04dee564df35153d98899bb6ddfb46f86ccf0646ff"],"state_sha256":"142a56e677330dba93ec6e60a405fc5db02c47bbe3eb775e9be90bbc23fecd3c"}