{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2012:MSNZPGEWZQVD3QLWMJQUT3QZZ2","short_pith_number":"pith:MSNZPGEW","schema_version":"1.0","canonical_sha256":"649b979896cc2a3dc176626149ee19cea8dca79e463f1a431aeeb3a3965007d2","source":{"kind":"arxiv","id":"1209.1895","version":1},"attestation_state":"computed","paper":{"title":"Vibrational temperature of the adlayer in \"hot atom\" reaction mechanism","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Massimo Tomellini","submitted_at":"2012-09-10T07:41:42Z","abstract_excerpt":"Hot-atoms reactions mechanisms bring about reaction rates which are several orders of magnitude higher than those expected in the case of ad-atoms which have thermalized with the surface. This paper addresses the issue of a possible thermodynamic characterization of the adlayer under reactive conditions and at the steady state. In turn, this implies to tackle the question of determining the temperature of the ad-atoms. This is done by means of a nonequilibrium statistical thermodynamic approach, by exploiting a suitable definition of the entropy. The interplay between reaction rate, vibrationa"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1209.1895","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2012-09-10T07:41:42Z","cross_cats_sorted":[],"title_canon_sha256":"c86753f331619c02d4f0162f05d810d386bf4f39d28c3f76088ca5f69a0dac4d","abstract_canon_sha256":"73db6f404435880cb917bd4d4f9f2dd8d5f9b1ecaf300c76d6a36c75e9def6f0"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:54:37.921380Z","signature_b64":"pRyxZL1FngFXvJWhervIi754d60+MVKiXpefsjwbngmeHrZXXjo3q4x7L+fsIp69454oIM2YXT3VnLbIy7e6Cw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"649b979896cc2a3dc176626149ee19cea8dca79e463f1a431aeeb3a3965007d2","last_reissued_at":"2026-05-18T01:54:37.920615Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:54:37.920615Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Vibrational temperature of the adlayer in \"hot atom\" reaction mechanism","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Massimo Tomellini","submitted_at":"2012-09-10T07:41:42Z","abstract_excerpt":"Hot-atoms reactions mechanisms bring about reaction rates which are several orders of magnitude higher than those expected in the case of ad-atoms which have thermalized with the surface. This paper addresses the issue of a possible thermodynamic characterization of the adlayer under reactive conditions and at the steady state. In turn, this implies to tackle the question of determining the temperature of the ad-atoms. This is done by means of a nonequilibrium statistical thermodynamic approach, by exploiting a suitable definition of the entropy. The interplay between reaction rate, vibrationa"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1209.1895","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1209.1895","created_at":"2026-05-18T01:54:37.920738+00:00"},{"alias_kind":"arxiv_version","alias_value":"1209.1895v1","created_at":"2026-05-18T01:54:37.920738+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1209.1895","created_at":"2026-05-18T01:54:37.920738+00:00"},{"alias_kind":"pith_short_12","alias_value":"MSNZPGEWZQVD","created_at":"2026-05-18T12:27:14.488303+00:00"},{"alias_kind":"pith_short_16","alias_value":"MSNZPGEWZQVD3QLW","created_at":"2026-05-18T12:27:14.488303+00:00"},{"alias_kind":"pith_short_8","alias_value":"MSNZPGEW","created_at":"2026-05-18T12:27:14.488303+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/MSNZPGEWZQVD3QLWMJQUT3QZZ2","json":"https://pith.science/pith/MSNZPGEWZQVD3QLWMJQUT3QZZ2.json","graph_json":"https://pith.science/api/pith-number/MSNZPGEWZQVD3QLWMJQUT3QZZ2/graph.json","events_json":"https://pith.science/api/pith-number/MSNZPGEWZQVD3QLWMJQUT3QZZ2/events.json","paper":"https://pith.science/paper/MSNZPGEW"},"agent_actions":{"view_html":"https://pith.science/pith/MSNZPGEWZQVD3QLWMJQUT3QZZ2","download_json":"https://pith.science/pith/MSNZPGEWZQVD3QLWMJQUT3QZZ2.json","view_paper":"https://pith.science/paper/MSNZPGEW","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1209.1895&json=true","fetch_graph":"https://pith.science/api/pith-number/MSNZPGEWZQVD3QLWMJQUT3QZZ2/graph.json","fetch_events":"https://pith.science/api/pith-number/MSNZPGEWZQVD3QLWMJQUT3QZZ2/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/MSNZPGEWZQVD3QLWMJQUT3QZZ2/action/timestamp_anchor","attest_storage":"https://pith.science/pith/MSNZPGEWZQVD3QLWMJQUT3QZZ2/action/storage_attestation","attest_author":"https://pith.science/pith/MSNZPGEWZQVD3QLWMJQUT3QZZ2/action/author_attestation","sign_citation":"https://pith.science/pith/MSNZPGEWZQVD3QLWMJQUT3QZZ2/action/citation_signature","submit_replication":"https://pith.science/pith/MSNZPGEWZQVD3QLWMJQUT3QZZ2/action/replication_record"}},"created_at":"2026-05-18T01:54:37.920738+00:00","updated_at":"2026-05-18T01:54:37.920738+00:00"}