{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2022:N33AEEIIVZMF2VYS3EAZJFCP4A","short_pith_number":"pith:N33AEEII","canonical_record":{"source":{"id":"2209.13955","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-09-28T09:38:12Z","cross_cats_sorted":[],"title_canon_sha256":"65d1b62f6a3f9db08643917ba4ec7629d9d6145b784d5b73badff40cba8f07b4","abstract_canon_sha256":"7cc22061a2d1e0ee7b82b15c519a8842861f1dd5f89c7a07e8a5ba853e5d774b"},"schema_version":"1.0"},"canonical_sha256":"6ef6021108ae585d5712d90194944fe01d7d5086756b80e244a7496945b1a64d","source":{"kind":"arxiv","id":"2209.13955","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2209.13955","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"arxiv_version","alias_value":"2209.13955v1","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2209.13955","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"pith_short_12","alias_value":"N33AEEIIVZMF","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"pith_short_16","alias_value":"N33AEEIIVZMF2VYS","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"pith_short_8","alias_value":"N33AEEII","created_at":"2026-07-05T05:01:46Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2022:N33AEEIIVZMF2VYS3EAZJFCP4A","target":"record","payload":{"canonical_record":{"source":{"id":"2209.13955","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-09-28T09:38:12Z","cross_cats_sorted":[],"title_canon_sha256":"65d1b62f6a3f9db08643917ba4ec7629d9d6145b784d5b73badff40cba8f07b4","abstract_canon_sha256":"7cc22061a2d1e0ee7b82b15c519a8842861f1dd5f89c7a07e8a5ba853e5d774b"},"schema_version":"1.0"},"canonical_sha256":"6ef6021108ae585d5712d90194944fe01d7d5086756b80e244a7496945b1a64d","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T05:01:46.133608Z","signature_b64":"HtCmoFj62xiM7N4caD57kE/W1iM/4n5iqoGSs77mOSby8TMkN8GI6wfrKyeUdCCmavM7C3sm/kT9iCzgXNZRCg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"6ef6021108ae585d5712d90194944fe01d7d5086756b80e244a7496945b1a64d","last_reissued_at":"2026-07-05T05:01:46.133215Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T05:01:46.133215Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2209.13955","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T05:01:46Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"baR+2bDL6+ldKjsNz4/lIuj2zy0QgdfVCrVWMqy6Kyd5EPuv5Z2NgQre8sdCfuU1gKEyAwM9/4VkxX4/JvyHDQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-18T03:16:23.589994Z"},"content_sha256":"48bc2a229e42fa6dd25f4f382ee194d103ff66c1a9c6f9ae54f3e66fa49d7341","schema_version":"1.0","event_id":"sha256:48bc2a229e42fa6dd25f4f382ee194d103ff66c1a9c6f9ae54f3e66fa49d7341"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2022:N33AEEIIVZMF2VYS3EAZJFCP4A","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Dissolution and Recrystallization Behavior of Li3PS4 in Different Organic Solvents","license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Aamir I. Waidha, Bettina V. Lotsch, Blazej Grabowski, Christian Schneider, Juergen Janek, Kerstin Wissel, Luise M. Riegger, Oliver Clemens, Robert E. Dinnebier, Theodosios Famprikis, Wolfgang Ensinger, Yuji Ikeda","submitted_at":"2022-09-28T09:38:12Z","abstract_excerpt":"Solid state batteries can be built based on thiophosphate electrolytes such as beta-Li3PS4. For the preparation of these electrolytes, various solvent-based routes have been reported. For recycling of end-of-life solid state batteries based on such thiophosphates, we consider the development of dissolution and recrystallization strategies for the recovery of the model compound beta-Li3PS4. We show that recrystallization can only be performed in polar, slightly protic solvents such as N-methylformamide (NMF). The recrystallization is comprehensively studied, showing that it proceeds via an inte"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2209.13955","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2209.13955/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T05:01:46Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"ZWcshAqT60TRnLhgT9+rvvza7ERQVAzdJHugHWEmRQId7UlLUVv21Bxh7C3F9Kmf+g63W2KUHUdAK65cDqe/CA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-18T03:16:23.590533Z"},"content_sha256":"849df12ec01add652b24985a3b31ed9508cd17e8c06d5cf509ef86c028681583","schema_version":"1.0","event_id":"sha256:849df12ec01add652b24985a3b31ed9508cd17e8c06d5cf509ef86c028681583"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/N33AEEIIVZMF2VYS3EAZJFCP4A/bundle.json","state_url":"https://pith.science/pith/N33AEEIIVZMF2VYS3EAZJFCP4A/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/N33AEEIIVZMF2VYS3EAZJFCP4A/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-18T03:16:23Z","links":{"resolver":"https://pith.science/pith/N33AEEIIVZMF2VYS3EAZJFCP4A","bundle":"https://pith.science/pith/N33AEEIIVZMF2VYS3EAZJFCP4A/bundle.json","state":"https://pith.science/pith/N33AEEIIVZMF2VYS3EAZJFCP4A/state.json","well_known_bundle":"https://pith.science/.well-known/pith/N33AEEIIVZMF2VYS3EAZJFCP4A/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2022:N33AEEIIVZMF2VYS3EAZJFCP4A","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"7cc22061a2d1e0ee7b82b15c519a8842861f1dd5f89c7a07e8a5ba853e5d774b","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-09-28T09:38:12Z","title_canon_sha256":"65d1b62f6a3f9db08643917ba4ec7629d9d6145b784d5b73badff40cba8f07b4"},"schema_version":"1.0","source":{"id":"2209.13955","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2209.13955","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"arxiv_version","alias_value":"2209.13955v1","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2209.13955","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"pith_short_12","alias_value":"N33AEEIIVZMF","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"pith_short_16","alias_value":"N33AEEIIVZMF2VYS","created_at":"2026-07-05T05:01:46Z"},{"alias_kind":"pith_short_8","alias_value":"N33AEEII","created_at":"2026-07-05T05:01:46Z"}],"graph_snapshots":[{"event_id":"sha256:849df12ec01add652b24985a3b31ed9508cd17e8c06d5cf509ef86c028681583","target":"graph","created_at":"2026-07-05T05:01:46Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2209.13955/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Solid state batteries can be built based on thiophosphate electrolytes such as beta-Li3PS4. For the preparation of these electrolytes, various solvent-based routes have been reported. For recycling of end-of-life solid state batteries based on such thiophosphates, we consider the development of dissolution and recrystallization strategies for the recovery of the model compound beta-Li3PS4. We show that recrystallization can only be performed in polar, slightly protic solvents such as N-methylformamide (NMF). The recrystallization is comprehensively studied, showing that it proceeds via an inte","authors_text":"Aamir I. Waidha, Bettina V. Lotsch, Blazej Grabowski, Christian Schneider, Juergen Janek, Kerstin Wissel, Luise M. Riegger, Oliver Clemens, Robert E. Dinnebier, Theodosios Famprikis, Wolfgang Ensinger, Yuji Ikeda","cross_cats":[],"headline":"","license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-09-28T09:38:12Z","title":"Dissolution and Recrystallization Behavior of Li3PS4 in Different Organic Solvents"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2209.13955","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:48bc2a229e42fa6dd25f4f382ee194d103ff66c1a9c6f9ae54f3e66fa49d7341","target":"record","created_at":"2026-07-05T05:01:46Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"7cc22061a2d1e0ee7b82b15c519a8842861f1dd5f89c7a07e8a5ba853e5d774b","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-09-28T09:38:12Z","title_canon_sha256":"65d1b62f6a3f9db08643917ba4ec7629d9d6145b784d5b73badff40cba8f07b4"},"schema_version":"1.0","source":{"id":"2209.13955","kind":"arxiv","version":1}},"canonical_sha256":"6ef6021108ae585d5712d90194944fe01d7d5086756b80e244a7496945b1a64d","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"6ef6021108ae585d5712d90194944fe01d7d5086756b80e244a7496945b1a64d","first_computed_at":"2026-07-05T05:01:46.133215Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T05:01:46.133215Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"HtCmoFj62xiM7N4caD57kE/W1iM/4n5iqoGSs77mOSby8TMkN8GI6wfrKyeUdCCmavM7C3sm/kT9iCzgXNZRCg==","signature_status":"signed_v1","signed_at":"2026-07-05T05:01:46.133608Z","signed_message":"canonical_sha256_bytes"},"source_id":"2209.13955","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:48bc2a229e42fa6dd25f4f382ee194d103ff66c1a9c6f9ae54f3e66fa49d7341","sha256:849df12ec01add652b24985a3b31ed9508cd17e8c06d5cf509ef86c028681583"],"state_sha256":"7292b58db520ca6d05f420c53176e45ef54fcb70c5e1e7d72f8354ffb5e9c1a5"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"brzCFjTgFy2EmfV3JOdhQn46F/RMKghjxvQ9hkrtpdDejKkpQvjrc9SJEP0TeelJGdfgrMVQ1dIyq/EMx8EwDA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-18T03:16:23.596130Z","bundle_sha256":"ca73c12f2345224a04f85c4281e4ba41b5029d6540acfa27d55ee39e454b239c"}}