{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2016:N3IEZ6AOAERICF2CTWWXR2XJ2H","short_pith_number":"pith:N3IEZ6AO","canonical_record":{"source":{"id":"1609.03685","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-09-13T05:38:37Z","cross_cats_sorted":[],"title_canon_sha256":"19e81710b088eb8ef4f0e4ab5e0d95e5ada64e60ceb2b476d00b0a5299922ddb","abstract_canon_sha256":"1005e9820c3aadfecf8c85ea76e05bf1e6ec12944ac2552a3b764699624f11d8"},"schema_version":"1.0"},"canonical_sha256":"6ed04cf80e01228117429dad78eae9d1e2f56ccc4e71c6a11d7f821ac17adb9d","source":{"kind":"arxiv","id":"1609.03685","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1609.03685","created_at":"2026-05-18T00:54:29Z"},{"alias_kind":"arxiv_version","alias_value":"1609.03685v1","created_at":"2026-05-18T00:54:29Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1609.03685","created_at":"2026-05-18T00:54:29Z"},{"alias_kind":"pith_short_12","alias_value":"N3IEZ6AOAERI","created_at":"2026-05-18T12:30:32Z"},{"alias_kind":"pith_short_16","alias_value":"N3IEZ6AOAERICF2C","created_at":"2026-05-18T12:30:32Z"},{"alias_kind":"pith_short_8","alias_value":"N3IEZ6AO","created_at":"2026-05-18T12:30:32Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2016:N3IEZ6AOAERICF2CTWWXR2XJ2H","target":"record","payload":{"canonical_record":{"source":{"id":"1609.03685","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-09-13T05:38:37Z","cross_cats_sorted":[],"title_canon_sha256":"19e81710b088eb8ef4f0e4ab5e0d95e5ada64e60ceb2b476d00b0a5299922ddb","abstract_canon_sha256":"1005e9820c3aadfecf8c85ea76e05bf1e6ec12944ac2552a3b764699624f11d8"},"schema_version":"1.0"},"canonical_sha256":"6ed04cf80e01228117429dad78eae9d1e2f56ccc4e71c6a11d7f821ac17adb9d","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:54:29.775307Z","signature_b64":"p9f1fxy/JYi7lgFHbwZOIZRqJihTpryLWepaB3ngWphgAxnrAwyjQMLlljCM5htRqHPjRBtZEkxXuSjhPhTiBg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"6ed04cf80e01228117429dad78eae9d1e2f56ccc4e71c6a11d7f821ac17adb9d","last_reissued_at":"2026-05-18T00:54:29.774590Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:54:29.774590Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1609.03685","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:54:29Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"qgLvLJL7rCU8TnjIPRpmlHhK3Vd7nqVCv9GHX8itQn+3KBMjDUk2IauswLar+kuFOfzvuoa1Scx/EQPfobyFCw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-23T15:47:44.370846Z"},"content_sha256":"742bb22190dddeb79ffbcdcfd46b6484c4590ba2e7a0f75fa0dd3335802b9d32","schema_version":"1.0","event_id":"sha256:742bb22190dddeb79ffbcdcfd46b6484c4590ba2e7a0f75fa0dd3335802b9d32"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2016:N3IEZ6AOAERICF2CTWWXR2XJ2H","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Effects of Herzberg--Teller vibronic coupling on coherent excitation energy transfer","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Hou-Dao Zhang, Qin Qiao, Rui-Xue Xu, YiJing Yan","submitted_at":"2016-09-13T05:38:37Z","abstract_excerpt":"In this work, we study the effects of non-Condon vibronic coupling on the quantum coherence of excitation energy transfer, via the exact dissipaton-equation-of-motion (DEOM) evaluations on excitonic model systems. Field-triggered excitation energy transfer dynamics and two dimensional coherent spectroscopy are simulated for both Condon and non-Condon vibronic couplings. Our results clearly demonstrate that the non-Condon vibronic coupling intensifies the dynamical electronic-vibrational energy transfer and enhances the total system-and-bath quantum coherence. Moreover, the hybrid bath dynamics"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1609.03685","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:54:29Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"1KWYOsELzhoTt1zOORVeGgbMl/ZrTBpvsB7f5HMAyjwKxs6IlmEbAxRJCFZoGy7d/iK1o4anypS4uMwER4PcCQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-23T15:47:44.371192Z"},"content_sha256":"71cb46e5efdf862db3fb121df6d35c02d2f3cee2c992273dc7a9bc348220a14d","schema_version":"1.0","event_id":"sha256:71cb46e5efdf862db3fb121df6d35c02d2f3cee2c992273dc7a9bc348220a14d"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/N3IEZ6AOAERICF2CTWWXR2XJ2H/bundle.json","state_url":"https://pith.science/pith/N3IEZ6AOAERICF2CTWWXR2XJ2H/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/N3IEZ6AOAERICF2CTWWXR2XJ2H/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-23T15:47:44Z","links":{"resolver":"https://pith.science/pith/N3IEZ6AOAERICF2CTWWXR2XJ2H","bundle":"https://pith.science/pith/N3IEZ6AOAERICF2CTWWXR2XJ2H/bundle.json","state":"https://pith.science/pith/N3IEZ6AOAERICF2CTWWXR2XJ2H/state.json","well_known_bundle":"https://pith.science/.well-known/pith/N3IEZ6AOAERICF2CTWWXR2XJ2H/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2016:N3IEZ6AOAERICF2CTWWXR2XJ2H","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"1005e9820c3aadfecf8c85ea76e05bf1e6ec12944ac2552a3b764699624f11d8","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-09-13T05:38:37Z","title_canon_sha256":"19e81710b088eb8ef4f0e4ab5e0d95e5ada64e60ceb2b476d00b0a5299922ddb"},"schema_version":"1.0","source":{"id":"1609.03685","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1609.03685","created_at":"2026-05-18T00:54:29Z"},{"alias_kind":"arxiv_version","alias_value":"1609.03685v1","created_at":"2026-05-18T00:54:29Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1609.03685","created_at":"2026-05-18T00:54:29Z"},{"alias_kind":"pith_short_12","alias_value":"N3IEZ6AOAERI","created_at":"2026-05-18T12:30:32Z"},{"alias_kind":"pith_short_16","alias_value":"N3IEZ6AOAERICF2C","created_at":"2026-05-18T12:30:32Z"},{"alias_kind":"pith_short_8","alias_value":"N3IEZ6AO","created_at":"2026-05-18T12:30:32Z"}],"graph_snapshots":[{"event_id":"sha256:71cb46e5efdf862db3fb121df6d35c02d2f3cee2c992273dc7a9bc348220a14d","target":"graph","created_at":"2026-05-18T00:54:29Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"In this work, we study the effects of non-Condon vibronic coupling on the quantum coherence of excitation energy transfer, via the exact dissipaton-equation-of-motion (DEOM) evaluations on excitonic model systems. Field-triggered excitation energy transfer dynamics and two dimensional coherent spectroscopy are simulated for both Condon and non-Condon vibronic couplings. Our results clearly demonstrate that the non-Condon vibronic coupling intensifies the dynamical electronic-vibrational energy transfer and enhances the total system-and-bath quantum coherence. Moreover, the hybrid bath dynamics","authors_text":"Hou-Dao Zhang, Qin Qiao, Rui-Xue Xu, YiJing Yan","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-09-13T05:38:37Z","title":"Effects of Herzberg--Teller vibronic coupling on coherent excitation energy transfer"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1609.03685","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:742bb22190dddeb79ffbcdcfd46b6484c4590ba2e7a0f75fa0dd3335802b9d32","target":"record","created_at":"2026-05-18T00:54:29Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"1005e9820c3aadfecf8c85ea76e05bf1e6ec12944ac2552a3b764699624f11d8","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-09-13T05:38:37Z","title_canon_sha256":"19e81710b088eb8ef4f0e4ab5e0d95e5ada64e60ceb2b476d00b0a5299922ddb"},"schema_version":"1.0","source":{"id":"1609.03685","kind":"arxiv","version":1}},"canonical_sha256":"6ed04cf80e01228117429dad78eae9d1e2f56ccc4e71c6a11d7f821ac17adb9d","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"6ed04cf80e01228117429dad78eae9d1e2f56ccc4e71c6a11d7f821ac17adb9d","first_computed_at":"2026-05-18T00:54:29.774590Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:54:29.774590Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"p9f1fxy/JYi7lgFHbwZOIZRqJihTpryLWepaB3ngWphgAxnrAwyjQMLlljCM5htRqHPjRBtZEkxXuSjhPhTiBg==","signature_status":"signed_v1","signed_at":"2026-05-18T00:54:29.775307Z","signed_message":"canonical_sha256_bytes"},"source_id":"1609.03685","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:742bb22190dddeb79ffbcdcfd46b6484c4590ba2e7a0f75fa0dd3335802b9d32","sha256:71cb46e5efdf862db3fb121df6d35c02d2f3cee2c992273dc7a9bc348220a14d"],"state_sha256":"1654b39322f3cece1f5c0e386fce8c85dc32b2578da46cfd142d6477536707ba"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"XlDpvMMSX0Zm5PATlYvEBXP7Qej3PQNWZz/ejXW0QzBfDt6rAMzuasAowA9m5ez6rW9y44qIQzGTvi8PREdACw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-23T15:47:44.373330Z","bundle_sha256":"025af8ecea7f60169777707460c035c9c9b11b32513e0ddf946fbadabeaa916f"}}