{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2017:NEWXKNDKAYR6G3ZEKWPKJKJOH6","short_pith_number":"pith:NEWXKNDK","schema_version":"1.0","canonical_sha256":"692d75346a0623e36f24559ea4a92e3f9f2cd8a89f519b2cff035f67dc9bba2a","source":{"kind":"arxiv","id":"1704.03505","version":1},"attestation_state":"computed","paper":{"title":"Non-uniqueness of quantum transition state theory and general dividing surfaces in the path integral space","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"quant-ph","authors_text":"Gregory A. Voth, Seogjoo Jang","submitted_at":"2017-04-11T19:29:46Z","abstract_excerpt":"Despite the fact that quantum mechanical principles do not allow the establishment of an exact quantum analogue of the classical transition state theory (TST), the development of a quantum TST (QTST) with a proper dynamical justification, while recovering the TST in the classical limit, has been a long standing theoretical challenge in chemical physics. One of the most recent efforts of this kind was put forth by Hele and Althorpe (HA) [ J. Chem. Phys. 138 , 084108 (2013)], which can be specified for any cyclically invariant dividing surface defined in the space of the imaginary time path inte"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1704.03505","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2017-04-11T19:29:46Z","cross_cats_sorted":[],"title_canon_sha256":"0d03d63f9a15f1e14f0c1819726c42f33d02946c81c77d697baa58b4b1796a1b","abstract_canon_sha256":"27245d62a06378edf122048fc6633c583af8c5875831bf1bd329b93eea337afc"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:43:50.711593Z","signature_b64":"8sFP3u5irxme6VARtwKJU6e3X4I3V8aKSaZQrRX6l8vQ2mVehkRKzmiWRB8LgA3PrmS3EnZ0/kMPqqyYDPWoAA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"692d75346a0623e36f24559ea4a92e3f9f2cd8a89f519b2cff035f67dc9bba2a","last_reissued_at":"2026-05-18T00:43:50.711072Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:43:50.711072Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Non-uniqueness of quantum transition state theory and general dividing surfaces in the path integral space","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"quant-ph","authors_text":"Gregory A. Voth, Seogjoo Jang","submitted_at":"2017-04-11T19:29:46Z","abstract_excerpt":"Despite the fact that quantum mechanical principles do not allow the establishment of an exact quantum analogue of the classical transition state theory (TST), the development of a quantum TST (QTST) with a proper dynamical justification, while recovering the TST in the classical limit, has been a long standing theoretical challenge in chemical physics. One of the most recent efforts of this kind was put forth by Hele and Althorpe (HA) [ J. Chem. Phys. 138 , 084108 (2013)], which can be specified for any cyclically invariant dividing surface defined in the space of the imaginary time path inte"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1704.03505","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1704.03505","created_at":"2026-05-18T00:43:50.711150+00:00"},{"alias_kind":"arxiv_version","alias_value":"1704.03505v1","created_at":"2026-05-18T00:43:50.711150+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1704.03505","created_at":"2026-05-18T00:43:50.711150+00:00"},{"alias_kind":"pith_short_12","alias_value":"NEWXKNDKAYR6","created_at":"2026-05-18T12:31:31.346846+00:00"},{"alias_kind":"pith_short_16","alias_value":"NEWXKNDKAYR6G3ZE","created_at":"2026-05-18T12:31:31.346846+00:00"},{"alias_kind":"pith_short_8","alias_value":"NEWXKNDK","created_at":"2026-05-18T12:31:31.346846+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/NEWXKNDKAYR6G3ZEKWPKJKJOH6","json":"https://pith.science/pith/NEWXKNDKAYR6G3ZEKWPKJKJOH6.json","graph_json":"https://pith.science/api/pith-number/NEWXKNDKAYR6G3ZEKWPKJKJOH6/graph.json","events_json":"https://pith.science/api/pith-number/NEWXKNDKAYR6G3ZEKWPKJKJOH6/events.json","paper":"https://pith.science/paper/NEWXKNDK"},"agent_actions":{"view_html":"https://pith.science/pith/NEWXKNDKAYR6G3ZEKWPKJKJOH6","download_json":"https://pith.science/pith/NEWXKNDKAYR6G3ZEKWPKJKJOH6.json","view_paper":"https://pith.science/paper/NEWXKNDK","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1704.03505&json=true","fetch_graph":"https://pith.science/api/pith-number/NEWXKNDKAYR6G3ZEKWPKJKJOH6/graph.json","fetch_events":"https://pith.science/api/pith-number/NEWXKNDKAYR6G3ZEKWPKJKJOH6/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/NEWXKNDKAYR6G3ZEKWPKJKJOH6/action/timestamp_anchor","attest_storage":"https://pith.science/pith/NEWXKNDKAYR6G3ZEKWPKJKJOH6/action/storage_attestation","attest_author":"https://pith.science/pith/NEWXKNDKAYR6G3ZEKWPKJKJOH6/action/author_attestation","sign_citation":"https://pith.science/pith/NEWXKNDKAYR6G3ZEKWPKJKJOH6/action/citation_signature","submit_replication":"https://pith.science/pith/NEWXKNDKAYR6G3ZEKWPKJKJOH6/action/replication_record"}},"created_at":"2026-05-18T00:43:50.711150+00:00","updated_at":"2026-05-18T00:43:50.711150+00:00"}