{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2012:U74VG32YW3BTQ3OZ3HN36QR52C","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"e54eaf67f11df8cf77fdb8df437f4c4a5f38dc037e1ad33c65d51b405516b611","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2012-08-30T21:44:24Z","title_canon_sha256":"c2e3bf2f03aa68db5763f9da41a6218ecafd60beacd3ca3388287a4f029c0225"},"schema_version":"1.0","source":{"id":"1208.6319","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1208.6319","created_at":"2026-05-18T03:41:19Z"},{"alias_kind":"arxiv_version","alias_value":"1208.6319v2","created_at":"2026-05-18T03:41:19Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1208.6319","created_at":"2026-05-18T03:41:19Z"},{"alias_kind":"pith_short_12","alias_value":"U74VG32YW3BT","created_at":"2026-05-18T12:27:23Z"},{"alias_kind":"pith_short_16","alias_value":"U74VG32YW3BTQ3OZ","created_at":"2026-05-18T12:27:23Z"},{"alias_kind":"pith_short_8","alias_value":"U74VG32Y","created_at":"2026-05-18T12:27:23Z"}],"graph_snapshots":[{"event_id":"sha256:da57bec788c9dd50f9c564d4ef26ed9050d5bf73e0369a019811a349090b3471","target":"graph","created_at":"2026-05-18T03:41:19Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We performed a systematic study of soft X-ray absorption spectroscopy in various manganese oxides and fluorides. Both Mn L-edges and ligand (O and F) K-edges are presented and compared with each other. Despite the distinct crystal structure and covalent/ionic nature in different systems, the Mn-L spectra fingerprint the Mn valence and spin states through spectral lineshape and energy position consistently and evidently. The clear O- and F- K pre-edge features in our high resolution spectra enable a quantitative definition of the molecular orbital diagram with different Mn valence. In addition,","authors_text":"Ruimin Qiao, Shishen Yan, Stephen J. Harris, Timothy Chin, Wanli Yang","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2012-08-30T21:44:24Z","title":"Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1208.6319","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:06b643c7f84712e8426f5bd34b7852da75ccdb214d6ae96d10a6d204011843bb","target":"record","created_at":"2026-05-18T03:41:19Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"e54eaf67f11df8cf77fdb8df437f4c4a5f38dc037e1ad33c65d51b405516b611","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2012-08-30T21:44:24Z","title_canon_sha256":"c2e3bf2f03aa68db5763f9da41a6218ecafd60beacd3ca3388287a4f029c0225"},"schema_version":"1.0","source":{"id":"1208.6319","kind":"arxiv","version":2}},"canonical_sha256":"a7f9536f58b6c3386dd9d9dbbf423dd0a1828d7686980b16351b95dc4c6a36c7","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"a7f9536f58b6c3386dd9d9dbbf423dd0a1828d7686980b16351b95dc4c6a36c7","first_computed_at":"2026-05-18T03:41:19.997781Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T03:41:19.997781Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"k7YWUZyszj67hgzcrpdZnaw6ZfzGMvNnjk+nYrv5O6QlA6be47NjslsiBXZXI6b5Ve0lSrsQPbzoRPD7vAHpDQ==","signature_status":"signed_v1","signed_at":"2026-05-18T03:41:19.998194Z","signed_message":"canonical_sha256_bytes"},"source_id":"1208.6319","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:06b643c7f84712e8426f5bd34b7852da75ccdb214d6ae96d10a6d204011843bb","sha256:da57bec788c9dd50f9c564d4ef26ed9050d5bf73e0369a019811a349090b3471"],"state_sha256":"85926c541dd7caf52274277b9d6399e905bcd69aeb0d5f07126fa6b6652414ef"}