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Black Hole Chemistry

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arxiv 1404.2126 v1 pith:A6T4MTFC submitted 2014-04-08 gr-qc hep-th

classification gr-qchep-th
keywords blackholechemistryholesmassphasebeenbehaviour
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The mass of a black hole has traditionally been identified with its energy. We describe a new perspective on black hole thermodynamics, one that identifies the mass of a black hole with chemical enthalpy, and the cosmological constant as thermodynamic pressure. This leads to an understanding of black holes from the viewpoint of chemistry, in terms of concepts such as Van der Waals fluids, reentrant phase transitions, and triple points. Both charged and rotating black holes exhibit novel chemical-type phase behaviour, hitherto unseen.

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Cited by 4 Pith papers

Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score. Full citation record

  1. Finite-cutoff Holographic Thermodynamics

    hep-th 2025-07 conditional novelty 6.0 of 10

    Finite-cutoff holography yields a thermodynamic duality between T^2-deformed CFTs and Schwarzschild-AdS black holes with a Dirichlet wall, including a teardrop coexistence curve with up to three states at one temperature.

  2. Heat and work in black hole thermodynamics via holography

    hep-th 2024-12 conditional novelty 6.0 of 10

    The paper derives first and second laws for composite black holes coupled through the boundary, with heat and work defined from boundary sources and bath energy flow.

  3. Specific Heats for Rotating Quantum BTZ Black Holes in Extended Thermodynamics

    hep-th 2025-02 conditional novelty 5.0 of 10

    For the rotating quantum BTZ black hole, the paper derives path-dependent heat capacities at constant pressure and volume with multiple positive and negative branches.

  4. Restricted Phase Space Thermodynamics of 4D Dyonic AdS Black Holes: Insights from Kaniadakis Statistics and Emergence of Superfluid $\lambda$-Phase Transition

    hep-th 2024-12 conditional novelty 4.0 of 10

    Using Kaniadakis entropy in restricted phase space thermodynamics, the authors report a superfluid-lambda-like phase transition and an ultra-large unstable black hole branch for 4D dyonic AdS black holes.

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