The role of plasma-molecule interactions on power and particle balance during detachment on the TCV tokamak

This paper shows experimental results from the TCV tokamak that indicate plasma-molecule interactions involving $D_2^+$ and possibly $D^-$ play an important role as sinks of energy (through hydrogenic radiation as well as dissociation) and particles during divertor detachment if low target temperatures ($< 3$ eV) are achieved. Both molecular activated recombination (MAR) and ion source reduction due to a power limitation effect are shown to be important in reducing the ion target flux during a density ramp. In contrast, the electron-ion recombination (EIR) ion sink is too small to play an important role in reducing the ion target flux. MAR or EIR do not occur during $N_2$ seeding induced detachment as the target temperatures are not sufficiently low. The impact of $D_2^+$ is shown to be underestimated in present (vibrationally unresolved) SOLPS-ITER simulations, which could result from an underestimated $D_2 + D^+ \rightarrow D_2^+ + D$ rate. The converged SOLPS-ITER simulations are post-processed with alternative reaction rates, resulting in considerable contributions of $D_2^+$ to particle and power losses as well as dissociation below the $D_2$ dissociation area. Those findings are in quantitative agreement with the experimental results.