Dark Matter Direct Detection with Quantum Dots

We propose using Quantum Dots as novel targets to probe sub-GeV dark matter-electron interactions. Quantum dots are nanocrystals of semiconducting material, which are commercially available, with gram-scale quantities suspended in liter-scale volumes of solvent. Quantum dots can be efficient scintillators, with near unity single-photon quantum yields, and their band-edge electronic properties are determined by their characteristic size, which can be precisely tuned. Examples include lead sulfide (PbS) and lead selenide (PbSe) quantum dots, which can be tuned to have sub-eV optical gaps. A dark-matter interaction can generate one or more electron-hole pairs (excitons), with the multi-exciton state decaying via the emission of two photons with an efficiency of about 10% of the single-photon quantum yield. An experimental setup using commercially available quantum dots and two photo-multiplier-tubes (PMTs) for detecting the coincident two-photon signal can already improve on existing dark-matter bounds, while using photodetectors with lower dark-count rates can improve on current constraints by orders of magnitude.