REVIEW 2 major objections 1 minor 42 references
After 100 Years of Quantum Mechanics: Toward a Constructive Observation-Centered Perspective
T0 review · 2 major / 1 minor · reviewed 2026-05-10 · grok-4.3
Pith's one-line read Quantum mechanics should treat observed signals as primary, with wave functions and Hamiltonians reconstructed as auxiliary structures from the data.
desk verdict This perspective calls for rebuilding quantum foundations around observed signals and finite-time constraints rather than wave functions, but it stays at the level of a program outline with no derivations or examples. read the letter →
The pith
A machine-rendered reading of the paper's core claim, the machinery that carries it, and where it could break.
The reading
What carries the argument
The signal-based spectral equation, which reformulates frequency analysis as an operator problem to enable reconstruction of auxiliary structures from observed signals.
What would settle it
A concrete calculation or experiment in which signal analysis under finite observation time fails to accurately reconstruct the spectrum or dynamics of a known quantum system without falling back on standard wave-function methods.
Extended reading notes
Core claim
The central claim is that quantum mechanics can be placed on a constructive footing by adopting an observation-centered viewpoint in which signals are primary, a signal-based spectral equation reformulates frequency analysis as an operator problem, and wave functions together with Hamiltonians are derived as auxiliary structures to rationalize the observed data, thereby incorporating finite accuracy and approximation as fundamental features from the outset.
Load-bearing premise
A signal-based spectral equation can be developed into a rigorous constructive theory that identifies essential degrees of freedom without circular dependence on the wave-function formalism it aims to subordinate.
Editorial extensions
If this is right
- Wave functions and Hamiltonians function only as rationalizing tools rather than starting points.
- A sharp accuracy transition appears that ties required observation time to the signal's effective spectral density.
- Approximation enters the foundations of quantum mechanics directly instead of as an afterthought.
- The framework supports effective descriptions for complex systems such as those in the molecular sciences.
Reading between the lines
- Simulations could focus computational effort on finite-time signal extraction rather than full state spaces.
- Direct data-driven identification of minimal degrees of freedom might become possible across quantum chemistry applications.
- Short-time quantum simulation techniques could gain systematic accuracy bounds from the observation-time transition.
Editorial analysis
A structured set of objections, weighed in public.
Referee Report
Summary. The manuscript is a perspective article critiquing the mismatch between the Hilbert-space formalism of quantum mechanics and practical constraints of finite-dimensional computations with finite accuracy. It proposes a new constructive mathematical program based on an observation-centered perspective, in which signals are the primary objects of analysis and wave functions and Hamiltonians are reconstructed as auxiliary structures. The proposal begins with a signal-based spectral equation reformulating frequency analysis as an operator problem, connects this to prolate Fourier theory, finite-observation-time spectral analysis, and short-time quantum simulation, and highlights a sharp accuracy transition relating necessary observation time to effective spectral density, with the goal of integrating approximation into the foundations for effective descriptions of complex quantum systems such as those in molecular sciences.
Significance. If the outlined program can be developed into a rigorous constructive theory, it would be significant for embedding finite-resource and approximation considerations directly into quantum foundations, offering a route to identify essential degrees of freedom without presupposing the full Hilbert-space structure. The explicit links to established results on prolate spheroidal functions and short-time simulation provide a credible mathematical anchor. However, the manuscript advances only a high-level conceptual outline without derivations, examples, or validations, so any significance remains prospective and contingent on future work.
major comments (2)
- Abstract: The signal-based spectral equation is introduced as the starting point for the observation-centered framework but is never formulated, derived, or illustrated. This equation is load-bearing for the central claim that signals can be treated as primary objects while subordinating wave functions, and its absence prevents evaluation of whether the approach can be made rigorous and non-circular.
- Abstract: The 'sharp accuracy transition' relating observation time to spectral density is presented as a key highlight demonstrating that approximation is fundamental, yet no quantitative characterization, derivation, or concrete example is supplied. Without this, the argument that the new perspective integrates approximation more directly than standard QM remains unsupported.
minor comments (1)
- The abstract invokes 'prolate Fourier theory' and 'short-time quantum simulation' without specific citations or indications of which results are being referenced, which would help readers trace the connections.
Simulated Author's Rebuttal
We thank the referee for their careful reading, positive assessment of the program's potential significance, and constructive identification of areas needing clarification. As a perspective article, the manuscript intentionally remains at a high conceptual level while pointing to established mathematical anchors; however, we agree that explicit formulations and characterizations will strengthen the presentation. We address each major comment below and will revise the manuscript accordingly.
read point-by-point responses
-
Referee: [—] Abstract: The signal-based spectral equation is introduced as the starting point for the observation-centered framework but is never formulated, derived, or illustrated. This equation is load-bearing for the central claim that signals can be treated as primary objects while subordinating wave functions, and its absence prevents evaluation of whether the approach can be made rigorous and non-circular.
Authors: We acknowledge the referee's point that the signal-based spectral equation requires more explicit treatment to support the central claim. Although the manuscript links it to prolate Fourier theory and finite-observation-time analysis, we agree an explicit statement is needed for evaluation. In revision we will add a short subsection that states the equation (reformulating frequency analysis as an operator eigenvalue problem on finite-time signals), sketches its derivation from observable data, and provides a simple illustrative example. This addition will demonstrate grounding in signals without presupposing the full Hilbert space, while preserving the perspective character of the article. revision: yes
-
Referee: [—] Abstract: The 'sharp accuracy transition' relating observation time to spectral density is presented as a key highlight demonstrating that approximation is fundamental, yet no quantitative characterization, derivation, or concrete example is supplied. Without this, the argument that the new perspective integrates approximation more directly than standard QM remains unsupported.
Authors: We accept that the sharp accuracy transition is highlighted without sufficient quantitative support in the current text. The transition arises from the spectral properties of the prolate spheroidal operator under finite observation time, but we agree a concrete characterization is required to substantiate the claim that approximation enters more directly than in standard QM. In the revised manuscript we will insert a quantitative description (relating necessary observation time T to the effective number of significant eigenvalues) together with a brief numerical example for a model signal, drawing directly on known results in prolate Fourier theory. A full general derivation for arbitrary quantum systems will remain part of the future constructive program. revision: partial
Circularity Check
No significant circularity in this perspective proposal
full rationale
The paper is a high-level conceptual perspective advocating an observation-centered framework with signals as primary objects. No mathematical derivations, theorems, or quantitative predictions are advanced in the provided text. The signal-based spectral equation is introduced as a starting point but not developed into any closed-form construction or fitted result that reduces to its own inputs. References to prolate Fourier theory and related results are external connections rather than self-citations carrying the central claim. The manuscript explicitly frames itself as a program proposal rather than a completed formal theory, so no load-bearing steps exist that could be circular by construction.
Assumptions & free parameters
assumptions (1)
- domain assumption Quantum mechanics admits a rigorous constructive theory built from signals as primary objects
Cite this review
Pith. "Pith review of After 100 Years of Quantum Mechanics: Toward a Constructive Observation-Centered Perspective." pith.science (2026). https://pith.science/paper/2604.11814
@misc{pith2026260411814,
author = {Pith},
title = {Pith review of: After 100 Years of Quantum Mechanics: Toward a Constructive Observation-Centered Perspective},
year = {2026},
howpublished = {\url{https://pith.science/paper/2604.11814}},
note = {Machine review of arXiv:2604.11814}
}
read the original abstract
Quantum mechanics owes much of its extraordinary success to a Hilbertian program of mathematical formalization. Yet, the formalism remains poorly aligned with the practical limitations of computations in finite dimensions and under finite accuracy. In this perspective, we argue that this mismatch points to the need for a new mathematical program: a rigorous constructive theory for effective descriptions to identify essential degrees of freedom. We propose an observation-centered point of view in which signals are treated as the primary objects of analysis, while wave functions and Hamiltonians are reconstructed as auxiliary structures to rationalize the observed data. Our starting point is a signal-based spectral equation that reformulates frequency analysis as an operator problem. We connect this point of view to results on prolate Fourier theory, spectral analysis with finite observation time, and short-time quantum simulation. We highlight a sharp accuracy transition relating necessary observation time to the effective spectral density of a signal for achieving accurate resolution. The resulting framework integrates approximation as a fundamental necessity more directly into the foundations of quantum mechanics and points toward a broader program for the effective description of complex quantum systems, such as those found in the molecular sciences.
Reference graph
Works this paper leans on
-
[1]
u ndung der Q uantenmechanik, Nachr. Ges. Wiss. G \
von Neumann, J. M athematische B egr \"u ndung der Q uantenmechanik, Nachr. Ges. Wiss. G \"o ttingen Math.-Phys. Kl. 1927, 1--57
work page 1927
-
[2]
von Neumann, J. Wahrscheinlichkeitstheoretischer Aufbau der Quantenmechanik, Nachrichten von der Gesellschaft der Wissenschaften zu G \"o ttingen, Mathematisch-Physikalische Klasse 1927, 1927, 245--272
work page 1927
-
[3]
von Neumann, J. Thermodynamik quantenmechanischer Gesamtheiten, Nachrichten von der Gesellschaft der Wissenschaften zu G \"o ttingen, Mathematisch-Physikalische Klasse 1927, 1927, 273--291
work page 1927
-
[4]
von Neumann, J. Allgemeine Eigenwerttheorie Hermitischer Funktionaloperatoren, Mathematische Annalen 1929, 102, 49--131
work page 1929
-
[5]
Wigner, E. P. The unreasonable effectiveness of mathematics in the natural sciences, Commun. Pure Appl. Math 1960, 13, 1-14
work page 1960
-
[6]
Reiher, M.;\ \ Wolf, A. Relativistic Quantum Chemistry: The Fundamental Theory of Molecular Science; Wiley-VCH: Weinheim, 2009
work page 2009
-
[7]
Dirac, P. A. M. Quantum Mechanics of Many-Electron Systems, Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character 1929, 123, 714--733
work page 1929
-
[8]
Cramer, C. J. Essentials of Computational Chemistry: Theories and Models; John Wiley & Sons: 2nd ed.; 2004
work page 2004
Show all 42 references
-
[9]
Introduction to Computational Chemistry; John Wiley & Sons: 3rd ed.; 2017
Jensen, F. Introduction to Computational Chemistry; John Wiley & Sons: 3rd ed.; 2017
2017
-
[10]
J.;\ \ Pollak, H
Landau, H. J.;\ \ Pollak, H. O. P rolate spheroidal wave functions, fourier analysis and uncertainty — III : T he dimension of the space of essentially time- and band-limited signals, Bell Syst. Tech. J. 1962, 41, 1295-1336
1962
-
[11]
O n bandwidth, Proc
Slepian, D. O n bandwidth, Proc. IEEE 1976, 64, 292-300
1976
-
[12]
Slepian, D.;\ \ Pollak, H. O. P rolate spheroidal wave functions, fourier analysis and uncertainty — I , Bell Syst. Tech. J. 1961, 40, 43-63
1961
-
[13]
J.;\ \ Pollak, H
Landau, H. J.;\ \ Pollak, H. O. P rolate spheroidal wave functions, fourier analysis and uncertainty — II , Bell Syst. Tech. J. 1961, 40, 65-84
1961
-
[14]
P rolate spheroidal wave functions, F ourier analysis and uncertainty — IV : E xtensions to many dimensions; generalized prolate spheroidal functions, Bell Syst
Slepian, D. P rolate spheroidal wave functions, F ourier analysis and uncertainty — IV : E xtensions to many dimensions; generalized prolate spheroidal functions, Bell Syst. Tech. J. 1964, 43, 3009-3057
1964
-
[15]
P rolate spheroidal wave functions, fourier analysis, and uncertainty — V : the discrete case, Bell Syst
Slepian, D. P rolate spheroidal wave functions, fourier analysis, and uncertainty — V : the discrete case, Bell Syst. Tech. J. 1978, 57, 1371-1430
1978
-
[16]
Quantisierung als Eigenwertproblem ( V ierte M itteilung), Annalen der Physik 1926, 81, 109--139
Schr \"o dinger, E. Quantisierung als Eigenwertproblem ( V ierte M itteilung), Annalen der Physik 1926, 81, 109--139
1926
-
[17]
R.;\ \ Reiher, M
Jacob, C. R.;\ \ Reiher, M. Spin densities in density functional theory, International Journal of Quantum Chemistry 2012, 112, 3661--3684
2012
-
[18]
Inhomogeneous Electron Gas, Physical Review 1964, 136, B864--B871
Hohenberg, P.;\ \ Kohn, W. Inhomogeneous Electron Gas, Physical Review 1964, 136, B864--B871
1964
-
[19]
Lieb, E. H. Density functionals for coulomb systems, International Journal of Quantum Chemistry 1983, 24, 243--277
1983
-
[20]
J.;\ \ Kaasbjerg, K.;\ \ Frederiksen, S
Mortensen, J. J.;\ \ Kaasbjerg, K.;\ \ Frederiksen, S. L.;\ \ N rskov, J. K.;\ \ Sethna, J. P.;\ \ Jacobsen, K. W. Bayesian Ensemble Approach to Error Estimation of Density Functional Theory Calculations, Physical Review Letters 2005, 95, 216401
2005
-
[21]
N.;\ \ Reiher, M
Simm, G. N.;\ \ Reiher, M. Systematic Error Estimation of Self-Consistent Field Calculations, Journal of Chemical Theory and Computation 2016, 12, 2762--2773
2016
-
[22]
Thirty years of density functional theory in computational chemistry: an assessment of 400 density functionals, Molecular Physics 2017, 115, 2315--2372
Mardirossian, N.;\ \ Head-Gordon, M. Thirty years of density functional theory in computational chemistry: an assessment of 400 density functionals, Molecular Physics 2017, 115, 2315--2372
2017
-
[23]
Goerigk, L.;\ \ Hansen, A.;\ \ Bauer, C.;\ \ Ehrlich, S.;\ \ Najibi, A.;\ \ Grimme, S. A look at the density functional theory zoo with the GMTKN55 database: numerical relative energies for main group chemistry, Physical Chemistry Chemical Physics 2022, 24, 15633--15670
2022
-
[24]
Field, R. W. Spectra and Dynamics of Small Molecules; volume 900 of Lecture Notes in Physics Springer: Cham, 2015
2015
-
[25]
Lefebvre-Brion, H.;\ \ Field, R. W. The Spectra and Dynamics of Diatomic Molecules; Elsevier Academic Press: Amsterdam, 2004
2004
-
[26]
Lefebvre-Brion, H.;\ \ Field, R. W. Perturbations in the Spectra of Diatomic Molecules; Academic Press: Orlando, 1986
1986
-
[27]
Spectra and dynamics of coupled vibrations in polyatomic molecules, Annual Review of Physical Chemistry 1990, 41, 839--874
Quack, M. Spectra and dynamics of coupled vibrations in polyatomic molecules, Annual Review of Physical Chemistry 1990, 41, 839--874
1990
-
[28]
Quack, M.;\ \ Merkt, F.,\ \ Eds.; Handbook of High-Resolution Spectroscopy; John Wiley & Sons, Ltd: Chichester, UK, 2011 3 Volumes
2011
-
[29]
G round and excited-state energies with analytic errors and short time evolution on a quantum computer, arXiv preprint arXiv: 2507.15148 2025,
Stroschein, T.;\ \ Castaldo, D.;\ \ Reiher, M. G round and excited-state energies with analytic errors and short time evolution on a quantum computer, arXiv preprint arXiv: 2507.15148 2025,
2025
-
[30]
P rolate S pheroidal W ave F unctions and the A ccuracy and D imensionality of S pectral A nalysis, arXiv preprint arXiv:2409.16584 2024,
Stroschein, T. P rolate S pheroidal W ave F unctions and the A ccuracy and D imensionality of S pectral A nalysis, arXiv preprint arXiv:2409.16584 2024,
2024
-
[31]
G.;\ \ Shen, X
Walter, G. G.;\ \ Shen, X. A. S ampling W ith Prolate Spheroidal Wave Functions , Sampl. Theory Signal Image Process. 2003, 2, 25--52
2003
-
[32]
C ommunication in the P resence of N oise, Proc
Shannon, C. C ommunication in the P resence of N oise, Proc. IRE 1949, 37, 10-21
1949
-
[33]
A n A pproximation F ramework for S ubspace-based M ethods in S pectral A nalysis with A ccuracy G uarantees, arXiv preprint arXiv:2505.07513 2025,
Stroschein, T. A n A pproximation F ramework for S ubspace-based M ethods in S pectral A nalysis with A ccuracy G uarantees, arXiv preprint arXiv:2505.07513 2025,
2025
-
[34]
J.;\ \ Wudarski, F.;\ \ Urbanek, M.;\ \ Hait, D.;\ \ Head-Gordon, M.;\ \ Whaley, K
Klymko, K.;\ \ Mejuto-Zaera, C.;\ \ Cotton, S. J.;\ \ Wudarski, F.;\ \ Urbanek, M.;\ \ Hait, D.;\ \ Head-Gordon, M.;\ \ Whaley, K. B.;\ \ Moussa, J.;\ \ Wiebe, N.;\ \ de Jong, W. A.;\ \ Tubman, N. M. Real-Time Evolution for Ultracompact Hamiltonian Eigenstates on Quantum Hardw...
2022
-
[35]
Simultaneous Estimation of Multiple Eigenvalues with Short-Depth Quantum Circuit on Early Fault-Tolerant Quantum Computers, Quantum 2023, 7, 1136
Ding, Z.;\ \ Lin, L. Simultaneous Estimation of Multiple Eigenvalues with Short-Depth Quantum Circuit on Early Fault-Tolerant Quantum Computers, Quantum 2023, 7, 1136
2023
-
[36]
Quantum Multiple Eigenvalue Gaussian filtered Search: an Efficient and Versatile Quantum Phase Estimation Method, Quantum 2024, 8, 1487
Ding, Z.;\ \ Li, H.;\ \ Lin, L.;\ \ Ni, H.;\ \ Ying, L.;\ \ Zhang, R. Quantum Multiple Eigenvalue Gaussian filtered Search: an Efficient and Versatile Quantum Phase Estimation Method, Quantum 2024, 8, 1487
2024
-
[37]
B.;\ \ Tubman, N
Shen, Y.;\ \ Camps, D.;\ \ Szasz, A.;\ \ Darbha, S.;\ \ Klymko, K.;\ \ Williams-Young, D. B.;\ \ Tubman, N. M.;\ \ Van Beeumen, R. Estimating Eigenenergies from Quantum Dynamics: A Unified Noise-Resilient Measurement-Driven Approach, Quantum 2025, 9, 1836
2025
-
[38]
Mathematical Problems, Bulletin of the American Mathematical Society 1902, 8, 437--479 English translation of Hilbert's 1900 Paris address
Hilbert, D. Mathematical Problems, Bulletin of the American Mathematical Society 1902, 8, 437--479 English translation of Hilbert's 1900 Paris address
1902
-
[39]
Zur Hilbertschen Beweistheorie, Mathematische Zeitschrift 1927, 26, 1--46
von Neumann, J. Zur Hilbertschen Beweistheorie, Mathematische Zeitschrift 1927, 26, 1--46
1927
-
[40]
Mathematische Grundlagen der Quantenmechanik; volume 38 of Die Grundlehren der mathematischen Wissenschaften in Einzeldarstellungen J
von Neumann, J. Mathematische Grundlagen der Quantenmechanik; volume 38 of Die Grundlehren der mathematischen Wissenschaften in Einzeldarstellungen J. Springer: Berlin, 1932
1932
-
[41]
The Logic of Quantum Mechanics, Annals of Mathematics 1936, 37, 823--843
Birkhoff, G.;\ \ von Neumann, J. The Logic of Quantum Mechanics, Annals of Mathematics 1936, 37, 823--843
1936
-
[42]
M olecule ‐S pecific U ncertainty Q uantification in Quantum Chemical Studies, Israel Journal of Chemistry 2022, 62,
Reiher, M. M olecule ‐S pecific U ncertainty Q uantification in Quantum Chemical Studies, Israel Journal of Chemistry 2022, 62,
2022
Reviewed May 10, 2026 · model on record in the stance chip above.
Discussion (0). Continue with ORCID to comment.