Aliphatic side chains on PAHs shift certain infrared band intensity ratios, especially in small molecules, which can mislead ionization-state estimates, though the main diagnostic grid still applies with possible calibration.
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Shiva is a new simulation tool that computes time-dependent dust size distributions and band gap energy evolution for HAC grains under photo-processing, sputtering, and shattering in specified interstellar conditions.
citing papers explorer
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The Influence of Aliphatic Components on the Aromatic Emission Characteristics of Polycyclic Aromatic Hydrocarbons
Aliphatic side chains on PAHs shift certain infrared band intensity ratios, especially in small molecules, which can mislead ionization-state estimates, though the main diagnostic grid still applies with possible calibration.
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Shiva: the dust destruction model
Shiva is a new simulation tool that computes time-dependent dust size distributions and band gap energy evolution for HAC grains under photo-processing, sputtering, and shattering in specified interstellar conditions.