Experimental measurements reveal large inverse Cl-KIEs (down to 0.492) in CID of three chlorohydrocarbons that decrease with collision energy from 0-60 eV, with both normal and inverse effects observed for dichloromethane.
Russell, Secondary isotope effects in the mass spectra of C 2D5OC2H5 and CD3CH2OC2H5
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Energy-dependent normal and unusually large inverse chlorine kinetic isotope effects of simple chlorohydrocarbons in collision-induced dissociation by gas chromatography-tandem mass spectrometry
Experimental measurements reveal large inverse Cl-KIEs (down to 0.492) in CID of three chlorohydrocarbons that decrease with collision energy from 0-60 eV, with both normal and inverse effects observed for dichloromethane.