Magnetoelectric effect in mixed-valence V12 cages is driven mainly by relocation of itinerant electrons, is strongly anisotropic, valence-state dependent, and detectable at room temperature.
The parameters of the Hamiltonian obtained from fitting theE= 0 data are kept intact and new parameters ∆Eo and ∆E ′ o are added to account for the change of orbital energy
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Magnetoelectric effect in the mixed valence polyoxovanadate cage V$_{12}$
Magnetoelectric effect in mixed-valence V12 cages is driven mainly by relocation of itinerant electrons, is strongly anisotropic, valence-state dependent, and detectable at room temperature.