Machine-learned many-body potentials from Poisson-Boltzmann calculations on clusters up to 48 colloids show that higher-order interactions reduce cohesion and eliminate broad gas-liquid phase separation, consistent with primitive model pair and triplet potentials.
Attractive double-layer interactions between calcium clay particles
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Models hollow charged nanoparticles as curved nanocapacitors to study nonlinear capacitance and symmetry breaking in confined electrolytes.
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Many-body attractions do not stabilize gas-liquid phase separation in aqueous dispersions of charged colloids within the Poisson-Boltzmann framework
Machine-learned many-body potentials from Poisson-Boltzmann calculations on clusters up to 48 colloids show that higher-order interactions reduce cohesion and eliminate broad gas-liquid phase separation, consistent with primitive model pair and triplet potentials.
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Unified Symmetry Breaking in Confined Electrolytes: Charge, Chemical Potential, and the Nonlinear Capacitance of Hollow Nanoparticles
Models hollow charged nanoparticles as curved nanocapacitors to study nonlinear capacitance and symmetry breaking in confined electrolytes.