The coherent-state transformation in QED-CC theory renormalizes correlation energy and ground state via the mean-field molecular dipole expectation value, using photon-added coherent states and breaking origin invariance for charged molecules.
The inequality between both expressions results from the non-vanishing commutator [e ˆQ, ˆUz] ̸= 0 , (9) between polaritonic cluster and CS transformation op- erators
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The coherent-state transformation in quantum electrodynamics coupled cluster theory
The coherent-state transformation in QED-CC theory renormalizes correlation energy and ground state via the mean-field molecular dipole expectation value, using photon-added coherent states and breaking origin invariance for charged molecules.