A second-order average Hamiltonian enables heteronuclear polarization transfer between spin-locked rare spins and anti-longitudinal abundant spins in liquids and MAS solids, achieving up to half the gyromagnetic ratio enhancement for 13C in practice.
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Heteronuclear Polarization Transfers Between Spin-locked and Anti-Longitudinal Spin States in the NMR of Liquids and Spinning Solids
A second-order average Hamiltonian enables heteronuclear polarization transfer between spin-locked rare spins and anti-longitudinal abundant spins in liquids and MAS solids, achieving up to half the gyromagnetic ratio enhancement for 13C in practice.