X-ray SHG in diamond becomes bulk-dominated by 1000 eV as the quadrupole response grows, with highest surface sensitivity near the carbon K-edge.
Keller,Ultrafast lasers: a comprehensive introduction to fundamental principles with prac- tical applications, Graduate texts in physics (Springer, Cham, 2021)
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The Surface Sensitivity of X-ray Second Harmonic Generation as a Function of Energy
X-ray SHG in diamond becomes bulk-dominated by 1000 eV as the quadrupole response grows, with highest surface sensitivity near the carbon K-edge.