Side-chain length in alkoxy-functionalized MOF-5 controls an entropy-driven PTE-to-NTE thermal expansion crossover.
Frustrated flexibility in metal- organic frameworks
2 Pith papers cite this work. Polarity classification is still indexing.
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Grafting flexible side chains onto MOFs triggers a crossover to glass-like thermal transport by turning acoustic phonons into critically damped modes via resonant hybridization and steric crowding.
citing papers explorer
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Side-Chain Tuning of Thermal-Expansion Crossover in Metal-Organic Frameworks
Side-chain length in alkoxy-functionalized MOF-5 controls an entropy-driven PTE-to-NTE thermal expansion crossover.
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Structurally Triggered Breakdown of the Phonon Gas Model in Crystalline Metal-Organic Frameworks
Grafting flexible side chains onto MOFs triggers a crossover to glass-like thermal transport by turning acoustic phonons into critically damped modes via resonant hybridization and steric crowding.