In ternary PEG mixtures, fluorescence lifetime follows a linear mixing rule with polymer proportion, and free volume theory captures the trend semi-quantitatively but leaves open questions about its precise application.
Haward, Occupied volume of liquids and polymers, Journal of Macromolecular Science, Part C4, 191 (1970)
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Response of fluorescent molecular rotors in ternary macromolecular mixtures
In ternary PEG mixtures, fluorescence lifetime follows a linear mixing rule with polymer proportion, and free volume theory captures the trend semi-quantitatively but leaves open questions about its precise application.