In ternary PEG mixtures, fluorescence lifetime follows a linear mixing rule with polymer proportion, and free volume theory captures the trend semi-quantitatively but leaves open questions about its precise application.
Hao, The empty world - a view from the free volume concept and eyring’s rate process theory, Physical Chemistry Chemical Physics26, 26156 (2025)
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Response of fluorescent molecular rotors in ternary macromolecular mixtures
In ternary PEG mixtures, fluorescence lifetime follows a linear mixing rule with polymer proportion, and free volume theory captures the trend semi-quantitatively but leaves open questions about its precise application.