Copolymerization of PNIPAM-like monomers with hydrophobic or ionizable comonomers enables control of microgel volume phase transition temperature and internal morphology, with external stimuli providing additional switching.
Does Flory–Rehner theory quantitatively describe the swelling of thermoresponsive microgels? Soft Matter 2017;13:8271–80
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Controlling microgel morphology and swelling behavior by copolymerization
Copolymerization of PNIPAM-like monomers with hydrophobic or ionizable comonomers enables control of microgel volume phase transition temperature and internal morphology, with external stimuli providing additional switching.