SERS and DFT analysis of Ln-citrate complexes shows relative intensity trends in bands near 935, 1060, and 1485 cm-1 from Dy to Lu, attributed to stronger Ln-O bonding and symmetry effects.
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Surface-enhanced Raman scattering and density functional theory study of selected-lanthanide-citrate complexes (lanthanide: Tb, Dy, Ho, Er, Tm, Yb and Lu)
SERS and DFT analysis of Ln-citrate complexes shows relative intensity trends in bands near 935, 1060, and 1485 cm-1 from Dy to Lu, attributed to stronger Ln-O bonding and symmetry effects.