Numerical tests on coupled oscillator models show that the local diabatic representation converges faster than the Born-Huang approach for strong vibronic couplings.
Baer ,\ @noop title Beyond Born-Oppenheimer : Conical Intersections and Electronic Non-Adiabatic Coupling Terms \ ( publisher Wiley ,\ address Hoboken, N.J ,\ year 2006 ) NoStop
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Exponential convergence of the local diabatic representation for nonadiabatic models
Numerical tests on coupled oscillator models show that the local diabatic representation converges faster than the Born-Huang approach for strong vibronic couplings.