Copolymerization of PNIPAM-like monomers with hydrophobic or ionizable comonomers enables control of microgel volume phase transition temperature and internal morphology, with external stimuli providing additional switching.
An anionic shell shields a cationic core allowing for uptake and release of polyelectrolytes within core–shell responsive microgels
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Controlling microgel morphology and swelling behavior by copolymerization
Copolymerization of PNIPAM-like monomers with hydrophobic or ionizable comonomers enables control of microgel volume phase transition temperature and internal morphology, with external stimuli providing additional switching.