Aliphatic side chains on PAHs shift certain infrared band intensity ratios, especially in small molecules, which can mislead ionization-state estimates, though the main diagnostic grid still applies with possible calibration.
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The Influence of Aliphatic Components on the Aromatic Emission Characteristics of Polycyclic Aromatic Hydrocarbons
Aliphatic side chains on PAHs shift certain infrared band intensity ratios, especially in small molecules, which can mislead ionization-state estimates, though the main diagnostic grid still applies with possible calibration.