Monte Carlo simulation of metal deposition on foreign substrates

The deposition of a metal on a foreign substrate is studied by means of grand canonical Monte Carlo simulations and a lattice-gas model with pair potential interactions between nearest neighbors. The influence of temperature and surface defects on adsorption isotherms and differential heat of adsorption is considered. The general trends can be explained in terms of the relative interactions between adsorbate atoms and substrate atoms. The systems Ag/Au(100), Ag/Pt(100), Au/Ag(100) and Pt/Ag(100) are analyzed as examples.