A Fragile-Strong Fluid Crossover and Universal Relaxation Times in a Confined Hard Disc Fluid

We show that a system of hard discs confined to a narrow channel exhibits a fragile-strong fluid crossover located at the maximum of the isobaric heat capacity and that the relaxation times for different channel widths fall onto a single master curve when rescaled by the relaxation times and temperatures of the crossover. Calculations of the configurational entropy and the inherent structure equation of state find that the crossover is related to properties of the jamming landscape for the model but that the Adams-Gibbs relation does not predict the relaxation behavior. We also show that a facilitated dynamics description of the system, where kinetically excited regions are identified with local packing arrangements of the discs, successfully describes the fragile-strong crossover.