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arxiv: 1208.3587 · v1 · pith:CRYVL47Ynew · submitted 2012-08-17 · ❄️ cond-mat.mtrl-sci · physics.chem-ph

A recoverable versatile photo-polymerization initiator catalyst

classification ❄️ cond-mat.mtrl-sci physics.chem-ph
keywords bmimdmiminitiatorphoto-polymerizationrecoverablebutyl-3-methylimizodiumcatalystcontrolled
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A photo-polymerization initiator based on an imidazolium and an oxometalate, viz., (BMIm)2(DMIm) PW12O40 (where, BMIm = 1-butyl-3-methylimizodium, DMIm = 3,3'-Dimethyl-1,1'-Diimidazolium) is reported. It polymerizes several industrially important monomers and is recoverable hence can be reused. The Mn and PDI are controlled and a reaction pathway is proposed.

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