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arxiv: 1605.03441 · v1 · pith:JCZLNCNEnew · submitted 2016-05-11 · ⚛️ physics.chem-ph

The chemistry induced by mechanical load

classification ⚛️ physics.chem-ph
keywords inducedloadmechanicalbondchemistrycpmddetailexample
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Results in the field of mechanochemistry are summarized. For example under mechanical load often a solvolysis is observed instead of a simple homolytic bond rupture. Also a mechanically induced redox reaction was reported experimentally and could be modelled theoretically. With CPMD simulations it is possible to understand multi-step mechanisms in full detail.

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