pith. sign in

arxiv: 1608.08430 · v2 · pith:2ZV5MYMOnew · submitted 2016-08-30 · ⚛️ physics.plasm-ph · physics.chem-ph

Free-energy functional of the Debye-H\"uckel model of simple fluids

classification ⚛️ physics.plasm-ph physics.chem-ph
keywords debye-hfunctionaluckelcorrelationfree-energyfunctionpairsimple
0
0 comments X
read the original abstract

The Debye-H\"uckel approximation to the free-energy of a simple fluid is written as a functional of the pair correlation function. This functional can be seen as the Debye-H\"uckel equivalent to the functional derived in the hyper-netted chain framework by Morita and Hiroike, as well as by Lado. It allows one to obtain the Debye-H\"uckel integral equation through a minimization with respect to the pair correlation function, leads to the correct form of the internal energy, and fulfills the virial theorem.

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.