Structural, electrical, magnetic, and flux pinning properties of YBCO/Ni superconducting composites: analyses and possible explanations

Samples of superconducting composite (100-x)YBa2Cu3O7-{\delta} + xNi (x = 1, 2.5, 5, 7.5, 10 and 15 wt.%) were synthesized. Scanning electron microscope (SEM) images revealed that the grain size of YBCO reduces gradually as Ni content is increased. At the same time segregation of Ni as NiO in patches forms throughout the composite. At low Ni wt.%, it was found that the superconducting state properties improved and then dropped with higher Ni wt.%. Segregated patches of NiO on different length scales were observed. The change in the structural and superconducting state parameters of YBCO and the variation of the magnetic critical current density with improved flux pinning in some composites with Ni additives were ascribed to the Jahn-Teller (JT) distortions and pinning of vortices due to antiferromagnetic NiO patches within the samples.