Performance analysis of a 2.45 GHz microwave plasma torch for CO₂ decomposition in gas swirl configuration

Microwave plasmas are a promising technology for energy-efficient CO$_{2}$ valorization via conversion of CO$_{2}$ into CO and O$_2$ using renewable energies. A 2.45 GHz microwave plasma torch with swirling CO$_{2}$ gas flow is studied in a large pressure (60-1000~mbar) and flow (5-100~slm) range. Two different modes of the plasma torch, depending on the operating pressure and microwave input power, are described: at pressures below 120~mbar the plasma fills most of the plasma torch volume whereas at pressures of about 120~mbar an abrupt contraction of the plasma in the center of the resonator is observed along with an increase of the gas temperature from 3000~K to 6000~K. The CO outflow is found to be proportional to the plasma effective surface and exhibits no significant dependence on the actual CO$_{2}$ flow injected into the reactor but only on the input power at certain pressure. Thermal dissociation calculations show that, even at the lowest pressures of this study, the observed conversion and energy efficiency are compatible with a thermal dissociation mechanism.