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arxiv: 2407.18473 · v1 · pith:ZRVPZY55new · submitted 2024-07-26 · ❄️ cond-mat.supr-con

Emergent spin-charge-orbital order in superconductor La₃Ni₂O₇

classification ❄️ cond-mat.supr-con
keywords orderemphmagneticsuperconductivitychargedensityexhibitsmechanism
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The bilayer nickelate La$_3$Ni$_2$O$_7$ (LNO) exhibits a remarkably high-temperature superconductivity of approximately 80 K under pressure, sparking considerable attentions. However, the nature of the spin, charge, and orbital order in LNO remains unknown, hindering the exploration of the mechanism of superconductivity. Here, supported by symmetry analysis and density functional theory calculations, we unravel a double strip ground state of LNO with alternating magnetic moments arrangements. Interestingly, a charge density wave emerges under this determined magnetic order. Such CDW phase exhibits a Pmnm space group with breathing deformation of the NiO$_6$ octahedra, where the stretching and shrinking of the octahedra correspond to the formation of \emph{d}$_{z^2}^1$\emph{d}$_{x^2-y^2}^1$ and \emph{d}$_{z^2}^1$ orbital order. Moreover, we build a first-principles-based Hamiltonian for LNO, which provides deeper insight into its peculiar magnetic order. Our work thus reveals a systematic spin-charge-orbital picture for LNO, which can be extended to other nickelate-based superconductors, paving the way for determining the mechanism of superconductivity.

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  1. Optical control of the crystal structure in the bilayer nickelate superconductor La3Ni2O7 via nonlinear phononics

    cond-mat.supr-con 2025-01 unverdicted novelty 6.0

    First-principles calculation shows selective excitation of an IR phonon mode in La3Ni2O7 produces a small nonlinear shift that moves the Ni-O-Ni bond angle closer to 180 degrees.