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arxiv: 2410.07479 · v1 · pith:XX5Z7S5M · submitted 2024-10-09 · cond-mat.mtrl-sci

Chiral effects at the metal center in Fe(III) spin crossover coordination salts

M Zaid Zaz , Wai Kiat Chin , Gauthami Viswan , Arjun Subedi , Esha Mishra , Kayleigh A McElveen , Binny Tamang , David Shapiro
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Alpha T NDiaye Rebecca Y Lai Peter A Dowben
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classification cond-mat.mtrl-sci
keywords coordinationcenterchiralcorecrossovermetalqsalsalts
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Evidence of chirality was observed at the Fe metal center in Fe(III) spin crossover coordination salts [Fe(qsal)2][ Ni(dmit)2] and [Fe(qsal)2](TCNQ)2 from X-ray absorption spectroscopy at the Fe 2p3/2 core threshold. This indicates the formation of chiral domains that influence the octahedral coordination on the Fe core.

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