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arxiv: 2410.18840 · v1 · pith:T3E7NOKTnew · submitted 2024-10-24 · ❄️ cond-mat.mtrl-sci · cond-mat.supr-con

Pressure-Induced Phase Transitions in Bilayer La₃Ni₂O₇

classification ❄️ cond-mat.mtrl-sci cond-mat.supr-con
keywords phaseclassicaldouble-layeredpressuresunderadditionallyalternatingbilayer
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La$_3$Ni$_2$O$_7$ exists in two polymorphs: an unconventional structure with alternating layers of single- and triple-layered nickel-oxygen octahedra, and a classical double-layered Ruddlesden-Popper phase. In this study, we report the growth of single crystals of classical double-layered La$_3$Ni$_2$O$_7$ using the floating zone method. Structural characterization under pressures up to 15.4 GPa reveals a gradual transition from orthorhombic to tetragonal symmetry near 12 GPa. Additionally, we present pressure and field-dependent electrical resistance measurements under pressures as high as 27.4 GPa, from which we construct a phase diagram.

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