Molecular Similarity and Water Diversity in Coeval Binary Disks: JWST/MIRI Observations of Sz 65 and Sz 66

We present JWST/MIRI MRS spectra of the wide-separation (projected separation $= 980$ au) binary protoplanetary disks Sz 65 (K7; $0.68 M_{\odot}$) and Sz 66 (M3; $0.30 M_{\odot}$), reduced using the uniform pipeline of the JWST Disk Infrared Spectral Chemistry Survey (JDISCS). Both disks show rich molecular emission, including H$_2$O, CO$_2$, HCN, C$_2$H$_2$, and OH. The scaled spectra of the two disks exhibit remarkably similar H$_2$O, CO$_2$, and HCN line emission in the 13-18 $\mu$m region, with the only notable difference being stronger C$_2$H$_2$ emission in the primary (Sz 65). Beyond 18 $\mu$m, the difference in H$_2$O line emission between the two disks increases. Both the flux ratios and the slab-model-derived mass ratios of cold to hot H$_2$O ($\sim 200$ K to $\sim 750$ K) and warm to hot H$_2$O ($\sim 450$ K to $\sim 750$ K) are significantly higher in the secondary (Sz 66). Because binary stars share nearly the same age and metallicity, and both disks appear compact in millimeter emission ($< 30$ au), we suggest that the excess cold H$_2$O in the secondary is best explained by its unstructured dust disk, in contrast to the primary, which shows gaps at 6 and 20 au. The enhanced cold water in the secondary is consistent with efficient pebble drift across the water snowline and increased H$_2$O vapor from the sublimation of icy mantles. Our results demonstrate that wide-separation binaries can serve as powerful control samples for isolating the impact of individual disk properties on inner-disk chemistry and evolution.