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arxiv: cond-mat/9411119 · v1 · submitted 1994-11-28 · ❄️ cond-mat

Long-Ranged Orientational Order in Dipolar Fluids

classification ❄️ cond-mat
keywords containerfluidthermodynamicdipolarlimitshapecalculationclaimed
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Recently Groh and Dietrich claimed the thermodynamic state of a dipolar fluid depends on the shape of the fluid's container. For example, a homogeneous fluid in a short fat container would phase separate when transferred to a tall skinny container of identical volume and temperature. Their calculation thus lacks a thermodynamic limit. We show that removal of demagnetizing fields restores the true, shape independent, thermodynamic limit. As a consequence, spontaneously magnetized liquids display inhomogeneous magnetization textures.

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