Production and deceleration of a pulsed beam of metastable NH (a ¹Delta) radicals

We report on the production of a pulsed molecular beam of metastable NH ($a ^1\Delta$) radicals and present first results on the Stark deceleration of the NH ($a ^1\Delta, J=2, M\Omega=-4$) radicals from 550 m/s to 330 m/s. The decelerated molecules are excited on the spin-forbidden $A ^3\Pi \leftarrow a ^1\Delta$ transition, and detected via their subsequent spontaneous fluorescence to the $X ^3\Sigma^{-}, v"=0$ ground-state. These experiments demonstrate the feasibility of our recently proposed scheme [Phys. Rev. A 64 (2001) 041401] to accumulate ground-state NH radicals in a magnetic trap.