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arxiv: 1001.3712 · v1 · submitted 2010-01-21 · ❄️ cond-mat.soft · cond-mat.stat-mech

Precipitation of water from aqueous mixtures with addition of hydrophilic ions

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords ionswateraqueousaveragecompositiondecreaseddomainshydrophilic
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We examine phase separation in aqueous mixtures at fixed amounts of hydrophilic monovalent ions. When water is the minority component, preferential solvation can stabilize water domains enriched with ions. This ion-induced precipitation occurs in wide ranges of the temperature and the average composition where the solvent would be in one-phase states without ions. The volume fraction of such water domains is decreased to zero as the interaction parameter $\chi$ (dependent on the temperature) is decreased toward a critical value for each average composition.

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