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Effect of Rare-earth Element Substitution in Superconducting R$_3$Ni$_2$O$_7$ Under Pressure

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arxiv 2309.06173 v1 pith:AFLFWBVA submitted 2023-09-12 cond-mat.supr-con cond-mat.str-el

classification cond-mat.supr-concond-mat.str-el
keywords elementundersubstitutionmaterialspairingpressurebilayerelectronic
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abstract

Recently, high temperature ($T_c\approx 80$K) superconductivity (SC) has been discovered in La$_3$Ni$_2$O$_7$ (LNO) under pressure. Question arises whether the transition temperature $T_c$ could be further enhanced under suitable conditions. A possible route for realizing higher $T_c$ is element substitution. Similar SC could appear in rare-earth (RE) R$_3$Ni$_2$O$_7$ (RNO, R=RE element) material series under pressure. The electronic properties in the RNO materials are dominated by the Ni $3d$ orbitals in the bilayer NiO$_2$ plane. In the strong coupling limit, the SC could be fully characterized by a bilayer single $3d_{x^2-y^2}$-orbital $t$-$J_{\parallel}$-$J_{\perp}$ model. Under RE element substitution from La to RE element, the lattice constant decreases and the electronic hopping increases, leading to stronger superexchanges between the $3d_{x^2-y^2}$ orbitals. Based on the slave-boson mean-field theory, we explore the pairing nature and the evolution of $T_c$ in RNO materials. Consequently, it is found that the element substitution does not alter the pairing nature, i.e. the inter-layer $s$-wave pairing is always favored in RNO. However, the $T_c$ increases from La to Sm and a nearly doubled $T_c$ is achieved for SmNO. This work provides evidence for possible higher $T_c$ R$_3$Ni$_2$O$_7$ materials, which may be realized in further experiments.

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  1. Orbital-selective electron correlations in high-$T_{\rm c}$ bilayer nickelates: from a global phase diagram to implications for spectroscopy

    cond-mat.supr-con 2024-12 conditional novelty 7.0 of 10

    A bilayer two-orbital Hubbard model of La3Ni2O7 shows orbital-selective correlations, with z2 electrons forming interlayer singlets, that reproduce key ARPES and optical conductivity features.

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