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arxiv: 2405.20651 · v1 · submitted 2024-05-31 · ❄️ cond-mat.soft · cond-mat.stat-mech

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Active Young-Dupr\'e Equation: How Self-organized Currents Stabilize Partial Wetting

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classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords activeequationsystemswettingcurrentsequilibriuminterfacessurface
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The Young-Dupr\'e equation is a cornerstone of the equilibrium theory of capillary and wetting phenomena. In the biological world, interfacial phenomena are ubiquitous, from the spreading of bacterial colonies to tissue growth and flocking of birds, but the description of such active systems escapes the realm of equilibrium physics. Here we show how a microscopic, mechanical definition of surface tension allows us to build an Active Young-Dupr\'e equation able to account for the partial wetting observed in simulations of active particles interacting via pairwise forces. Remarkably, the equation shows that the corresponding steady interfaces do not result from a simple balance between the surface tensions at play but instead emerge from a complex feedback mechanism. The interfaces are indeed stabilized by a drag force due to the emergence of steady currents, which are themselves a by-product of the symmetry breaking induced by the interfaces. These currents also lead to new physics by selecting the sizes and shapes of adsorbed droplets, breaking the equilibrium scale-free nature of the problem. Finally, we demonstrate a spectacular consequence of the negative value of the liquid-gas surface tensions in systems undergoing motility-induced phase separation: partially-immersed objects are expelled from the liquid phase, in stark contrast with what is observed in passive systems. All in all, our results lay the foundations for a theory of wetting in active systems.

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Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score.

  1. How active field theories couple to external potentials

    cond-mat.stat-mech 2026-03 unverdicted novelty 7.0

    Active field theories require a specific density-potential gradient coupling derived from microscopic persistence to reproduce nonequilibrium behaviors like boundary accumulation.