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Signature of Superconductivity in Pressurized Trilayer-nickelate Pr$_4$Ni$_3$O$_{10-\delta}$
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abstract
The discovery of high-temperature superconductivity in La$_3$Ni$_2$O$_7$ and La$_4$Ni$_3$O$_{10}$ under pressure has drawn extensive attention. Herein, we report systematic investigations on the evolutions of structure, magnetism, and electrical resistance of Pr$_4$Ni$_3$O$_{10-\delta}$ polycrystalline samples under various pressures. Pr$_4$Ni$_3$O$_{10-\delta}$ exhibits density wave transitions on Ni and Pr sublattices at about 158 K and 4.3 K, respectively, and the density wave can be progressively suppressed by pressure. A structural transformation from the monoclinic $P2_1/a$ space group to the tetragonal $I4/mmm$ occurs at around 20 GPa. An apparent drop in resistance with evident magnetic field dependence is observed as pressure above 20 GPa, indicating the emergence of superconductivity in Pr$_4$Ni$_3$O$_{10-\delta}$ polycrystalline samples. The discovery of the signature of superconductivity in Pr$_4$Ni$_3$O$_{10-\delta}$ broadens the family of nickelate superconductors and provides a new platform for investigating the mechanisms of superconductivity in the Ruddlesden-Popper phases of nickelates.
Forward citations
Cited by 2 Pith papers
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Evolution of magnetism in Ruddlesden-Popper bilayer nickelate revealed by muon spin relaxation
Muon spin relaxation finds long-range magnetic order below 161 K in La1.9Pr1.1Ni2O6.97 and short-range order below 30 K in oxygen-deficient La3Ni2O6.63, linking oxygen vacancies to suppressed magnetism.
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Unveiling the multiband metallic nature of the normal state in nickelate La3Ni2O7
Magnetoresistance of pressurized La3Ni2O7 follows a quasi-quadratic field dependence and extended Kohler scaling, leading the authors to conclude the normal state is a multiband metal.
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