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Discovery of a new molecular ion, HC7NH+, in TMC-1

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arxiv 2203.05617 v1 pith:GDZJ4HRY submitted 2022-03-10 astro-ph.GA

C. Cabezas , M. Agundez , N. Marcelino , B. Tercero , R. Fuentetaja , P. de Vicente , J. Cernicharo This is my paper
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keywords hc7nhhc7ncolumndensityderiveddiscoveryidentificationprotonated
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We report the detection of the protonated form of HC7N in TMC-1. The discovery of the cation HC7NH+ was carried out via the observation of nine harmonically related lines in the Q-band using the Yebes 40m radiotelescope. The observed frequencies allowed us to obtain the rotational constants B_0=553.938802(160)MHz and D_0=3.6292(705) Hz. The identification of HC7NH+ is further supported by accurate ab initio calculations. We derived a column density of (5.5+/-0.7)e10 cm-2, which constitutes another piece of evidence for the identification of the carrier. In addition, we revised the HC7N column density and we derived a new value of (2.1+/-0.2)e13cm-2. Hence, the abundance ratio HC7N/HC7NH+ is 380, while those for HC3N/HC3NH+ and HC5N/HC5NH+ are 230 and 240, respectively. Here, we discuss these results within the framework of a chemical model for protonated molecules in cold dense clouds.

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Cited by 1 Pith paper

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  1. Chemistry of Dark Molecular Clouds

    astro-ph.GA 2026-07 unverdicted novelty 2.0 of 10

    A comprehensive review arguing that the chemically rich cores TMC-1 CP and L1544 are representative molecular-cloud laboratories, and that complex organic molecule production is largely insensitive to metallicity.

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