High-precision mass measurements of the ground and isomeric states in ^(124,125)Ag

The masses of the ground and isomeric states in $^{124,125}$Ag have been measured using the phase-imaging ion-cyclotron-resonance technique at the JYFLTRAP double Penning trap mass spectrometer. The ground states of $^{124}$Ag and $^{125}$Ag were found to be 30(250) keV and 250(430) keV less bound but 36 and 110 times more precise than in the Atomic Mass Evaluation 2020, respectively. The excitation energy of $^{124}$Ag$^{m}$, ${E_x = 188.2(25)}$ keV, was determined for the first time. The new precise mass values have been utilised to study the evolution of nuclear structure via two-neutron separation energies. The impact on the astrophysical rapid neutron capture process has been investigated via neutron-capture reaction rate calculations. The precision measurements indicate a more linear trend in two-neutron separation energies and reduce the mass-related uncertainties for the neutron-capture rate of $^{124}$Ag$(n,\gamma)^{125}$Ag by a factor of around 100. The new mass values also improve the mass of $^{123}$Pd, previously measured using $^{124}$Ag as a reference.