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REVIEW 4 major objections 4 minor 42 references

Influence of gas flow rate on modes of reactive oxygen and nitrogen species in a grid-type surface dielectric barrier discharge

T0 review · 4 major / 4 minor · reviewed 2026-08-08 · deepseek-v4-flash

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Pith's one-line read This paper claims that the gas flow rate through a grid-type surface dielectric barrier discharge controls whether the plasma's chemistry settles into an ozone-dominated or a nitrogen-oxide-dominated mode, via the density of vibrationally…

desk verdict Good new flow-rate data for a grid SDBD, but the paper's central N2(v) mechanism is fitted input, not a tested result. read the letter →

arxiv 2502.04851 v1 pith:NGM7FCHZ submitted 2025-02-07 physics.plasm-ph physics.app-ph

Angie Natalia Torres Segura , Kazumasa Ikuse , Satoshi Hamaguchi , Andrew R. Gibson , Lars Schücke This is my paper · ORCID
classification physics.plasm-phphysics.app-ph
keywords dielectricbarrierdischargereactiveoxygenandnitrogenspeciesplasmachemistryopticalabsorptionspectroscopychemicalkineticssimulationmodetransitionvibrationalexcitationgasflowrate
verification ladder T0 review T1 audit T2 compute T3 formal

The pith

A machine-rendered reading of the paper's core claim, the machinery that carries it, and where it could break.

The reading

This paper tries to establish that the gas flow rate in a grid-type surface dielectric barrier discharge operated in dry synthetic air determines which of two chemical modes the plasma occupies: an ozone-dominated mode at high flow, and a nitrogen-oxide-dominated mode that emerges after a transition time at low flow. The authors measure $O_3$, $NO_2$, and $N_2O_5$ densities by optical absorption spectroscopy at flow rates from 0 to 10 slm and find that the $O_3$-to-$NO_x$ transition occurs at 0-2 slm but is absent at 4-10 slm. A two-zone zero-dimensional chemical kinetics model reproduces the measured $O_3$ dynamics and attributes the flow-rate effect to a lower density of highly vibrationally excited nitrogen, $N_2(v \ge 12)$, represented in the model by a reduced vibrational temperature at higher flow. If the mechanism is correct, flow rate provides a simple external control for plasma chemistry relevant to ozone generation, pollution remediation, and biomedical applications.

What carries the argument

The central object is the time-dependent vibrational temperature $T_v(t)$ of nitrogen, defined by $T_v = T_g + T_v^0(1 - \exp(-t/\tau_v))$, whose Maxwellian tail gives the density $n_{N_2(v \ge 12)} = n_{N_2}\exp(-12\Delta\varepsilon_v / (k_B T_v))$. This density drives the key reaction R9, $O + N_2(v) \rightarrow NO + N$, and the NO produced then consumes $O_3$ via R18, $O_3 + NO \rightarrow NO_2 + O_2$, switching the system from the ozone mode to the $NO_x$ mode. The two-zone model couples a plasma-near region and a gas-far region through diffusion, plasma-induced drift, and a flow-removal term, and its eight free parameters ($n_O$, $T_v^0$, $\tau_v$, $T_g$, $T_p$, $n_{N_2(A^3\Sigma)}$, $n_{O_2(a^1\Delta)}$, $r_N$) are fitted to the measured densities at each flow rate.

What would settle it

Measure the density of $N_2(v \ge 12)$ directly in the reactor at 0 slm and 10 slm using state-selective spectroscopy (e.g., vacuum-ultraviolet absorption or two-photon laser-induced fluorescence). The claimed mechanism predicts a significantly lower density at 10 slm at the time the transition would be expected; if the density is not lower, or if injecting pre-vibrationally excited $N_2$ into a high-flow gas stream does not restore the transition, the proposed flow-rate–vibrational-excitation link is falsified.

Watch

Extended reading notes

Core claim

The paper's central discovery is that the mode transition from the $O_3$ to the $NO_x$ state in this surface dielectric barrier discharge is governed by the gas flow rate through the density of $N_2(v \ge 12)$, the source of NO via $O + N_2(v) \rightarrow NO + N$. Experimentally, the transition is observed at low flow rates and not at high flow rates. The model captures this by assigning each flow rate a steady-state vibrational temperature $T_v^0$ and a rise time $\tau_v$: $T_v^0$ decreases from 6500 K at 0 slm to 4500 K at 5-10 slm, and $\tau_v$ increases from 18 s to 35 s, so that the computed $n_{N_2(v \ge 12)}$ is lower at high flow. The simulations follow the $O_3$ rise, peak, and decay at 0 slm within about 50% agreement, while the $NO_2$ and $N_2O_5$ dynamics deviate more strongly at high flow, where the role of vibrationally excited nitrogen is diminished. The authors conclude that this mechanism is the key factor for the absence of the mode transition at higher flow rates, and note that N-atom production becomes a potentially significant pathway for $NO_2$ formation in that regime.

Load-bearing premise

The conclusion that higher flow suppresses the ozone-to-NOx transition by reducing the density of vibrationally excited nitrogen is an input to the model, not a measured fact: the vibrational temperature and its rise time are fitted separately for each flow rate, and the assumed Maxwellian shape of the vibrational distribution is acknowledged in the paper to be experimentally unlikely.

Editorial extensions

If this is right

  • At high gas flow rates the discharge remains in the ozone-dominated mode, so raising the flow is a direct way to favor $O_3$ production over $NO_x$ production in applications such as water treatment and sterilization.
  • The mode transition is set by the slow build-up of vibrationally excited nitrogen (time constant $\tau_v$ of tens of seconds), so operating the discharge in short bursts—or with residence times shorter than $\tau_v$—should hold the ozone mode even at low flow.
  • Reactions R9 and R18 form the nonlinear switch pair: any measure that lowers the rate of $O + N_2(v) \rightarrow NO + N$ or that accelerates $O_3$ consumption will shift the transition time.
  • The fitted parameters show that suppressing the steady-state vibrational temperature from 6500 K to 4500 K is sufficient to prevent the transition, giving a quantitative target for flow-based mode control.

Reading between the lines

Editorial extensions of the paper, not claims the author makes directly.

  • If the Maxwellian vibrational distribution assumption in equations (4)-(5) is replaced by a more realistic non-equilibrium distribution, the fitted absolute values of $T_v^0$ would change, but the qualitative flow-rate dependence of $n_{N_2(v \ge 12)}$ could persist; the paper's mechanism is therefore testable at the level of the vibrational distribution shape itself.
  • The model's underprediction of $NO_2$ at high flow suggests that atomic nitrogen, not vibrationally excited $N_2$, may dominate $NO_x$ production in the high-flow regime; a direct measurement of N-atom densities (for example by two-photon absorption laser-induced fluorescence) would determine whether the proposed mechanism is incomplete.
  • The same residence-time argument may carry over to other plasma-chemical converters: any means of shortening the effective gas residence time—pulsed flow, oscillating gas velocity, or reactor geometry—might suppress the mode transition in the same way as raising the flow rate.
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Editorial analysis

A structured set of objections, weighed in public.

Desk editor's note, referee report, and a circularity audit.

Referee Report

4 major / 4 minor

Summary. The paper reports optical absorption spectroscopy measurements of O3, NO2, and N2O5 densities in a grid-type surface dielectric barrier discharge operated in dry synthetic air at flow rates from 0 to 10 slm. At low flow rates the system transitions from an O3-dominated to an NOx-dominated mode over tens of seconds, while at high flow rates no clear transition is observed. A two-zone zero-dimensional chemical kinetics model with eight free parameters is fitted to the measured density profiles. The authors attribute the flow-rate dependence of the mode transition to a flow-induced decrease in the density of vibrationally excited N2(v>12), represented in the model by a decreasing steady-state vibrational temperature T0_v and an increasing time constant tau_v with flow. The model reproduces O3 dynamics well at all flow rates, while NO2 and N2O5 agreement degrades at higher flow.

Significance. The experimental data set, covering absolute densities of key reactive species over a range of flow rates and operating times, is a useful contribution and the optical absorption methodology is well established. The two-zone model description is transparent, the reaction set is clearly documented, and the authors are commendably explicit about the non-uniqueness of their fitted parameters and the questionable validity of the Maxwellian vibrational distribution. If the central mechanistic claim were independently supported, the result would be significant for controlling SDBD mode transitions in applications. However, the claim as presented is not sufficiently supported: the key quantity nN2(v>12) is prescribed by hand-fitted parameters rather than derived from or measured against the flow physics, and alternative mechanisms such as gas heating are not excluded. The paper's strength is the honest and detailed presentation of a model that can be tuned to reproduce the data, not yet a validated mechanism.

major comments (4)
  1. [§IV (Eqs. 4–5), Table III, Fig. 9] The central mechanistic claim, that increasing gas flow suppresses the O3-to-NOx mode transition by reducing nN2(v>12), is not supported by the model as presented. nN2(v>12) is prescribed by Eqs. (4)–(5) with T0_v and tau_v as free parameters, and Table III shows T0_v declining from 6500 K at 0 slm to 4500 K at 8–10 slm while tau_v increases from 18 s to 35 s. Figure 9 therefore displays an input of the fit, not a derived or measured quantity. Because the flow dependence of nN2(v>12) is entirely imposed by these hand-set parameters, the agreement between measured and simulated O3 densities in Figs. 10–12 cannot validate the proposed mechanism; it only demonstrates that the model can be tuned to reproduce the data. The authors' own statement that the parameter combinations are not unique further weakens the inference. To support the claim, the model would need to derive the temporal evolution of nN2(v>=12) from a transport or kinetics equation that couples gas flow to vibrational excitation/loss, or the vibrational density would need to be measured independently.
  2. [§V.B, Table III] The sensitivity discussion states that an increase in T_g leads to an earlier mode transition, yet in Table III T_g is held at 310 K for all flow rates and T_p changes only from 335 K to 340 K. Longer residence times at low flow would be expected to increase gas heating, providing an alternative explanation for the early transition at low flow that the model does not test. Because the fitted gas temperatures are nearly flow-independent by construction, the model cannot discriminate between the proposed N2(v) mechanism and a thermal mechanism. A test that varies T_g or T_p while holding T0_v fixed would be required to show that vibrational excitation, rather than gas temperature, is the controlling factor.
  3. [Table III, tau_v trend] The fitted time constant tau_v increases from 18 s at 0 slm to 35 s at 6–10 slm. If higher gas flow reduced the density of vibrationally excited N2 by convective removal, one would expect the effective rise time of T_v to shorten, not lengthen, because the loss rate increases with flow. The monotonic increase of tau_v with flow appears to be an ad hoc adjustment that delays the transition at high flow rather than a physically motivated parameter; no rationale is given for why convection should slow the vibrational excitation or relaxation process. This inconsistency further undermines the credibility of the fitted parameter trends and, with them, the central claim.
  4. [§III.A, Figs. 6–7] The measured density profiles are presented without any error bars, confidence intervals, or uncertainty propagation from the Lambert–Beer analysis (Eq. 3). Given that the mode transition is identified from the temporal behavior of the measured curves and that the model is fit to these curves, the absence of uncertainty estimates leaves unquantified how clearly the transition is distinct at 2 slm versus 4 slm, and whether the simulated fits are within experimental error. The experimental foundation of the flow-dependent disappearance of the transition would be far more convincing if measurement uncertainties were reported.
minor comments (4)
  1. [§VI] The conclusion uses both "N2(v) with v ≥ 12" and "N2(v >12)" inconsistently; pick one notation and use it throughout the manuscript.
  2. [§IV, Eq. (8)] The notation "kflow;p,g" uses a semicolon that is puzzling; also the subscript "p,g" could be confused with "pg". Please clarify or rename this coefficient.
  3. [§II.A, §V.A] Units are typeset inconsistently: "0.0 ms-1" and "0.1 m -1" should be "0.0 m s^-1" and "0.1 m s^-1" respectively, with proper spacing and exponents.
  4. [Data Availability Statement] The data availability statement appears with garbled spacing and repeated words ("A V AILABILITY OF DAT A ST A TEMENT..."); this should be cleaned up before publication.

Circularity Check

1 steps flagged · score 7.0 of 10

Flow-rate dependence of N2(v>12) is a fitted input, not a measured or predicted result; the central mechanistic claim reduces to the hand-set values of T0v and tau_v in Table III.

  1. fitted input called prediction [Section IV, Eqs. (4)-(5); Table III; Section V.B, Figs. 9-12]
    "The temporal evolution of n N2(v ≥ 12) is given by: nN2(v) = nN2 Fv>12 = nN2 exp(− 12∆εv/kBTv) , (4) Tv = Tg + T0v(1 − exp(−t/τv)) (5) ... A comparison of figures 8 and 9 shows that an increase in gas flow rate leads to a decrease in n N2(v >12). This supports the hypothesis presented in the previous chapter, that this variation is a key factor for the absence of the mode transition at higher flow rates ... It should also be noted that the determined input parameters were mainly tailored to achieve a good match between measured and simulated O3 densities."

    nN2(v>12) is never measured and no transport equation is solved for it; Eqs. (4)-(5) prescribe it using the free parameters T0v and tau_v. Table III is constructed by fitting the model to the measured O3/NO2/N2O5 time profiles: T0v decreases from 6500 K at 0 slm to 4500 K at 6-10 slm, and tau_v increases from 18 s to 35 s. The flow dependence of nN2(v>12) shown in Fig. 9 is therefore an input of the fitting procedure, not an independent measurement or prediction. The paper itself concedes that the parameter combinations are non-unique and that the input parameters were tailored to match O3. Since the mode-transition timing is controlled by T0v and tau_v, the agreement in Figs.

full rationale

The experimental O3, NO2, and N2O5 time series are genuine external data, and the rate-coefficient table is compiled from independent literature, so the paper is not circular in those respects. The circularity lies in the mechanistic attribution. The model has eight free parameters, among them T0v and tau_v, which define nN2(v>12) through Eqs. (4)-(5). These parameters are chosen by hand to reproduce the measured transition timing at each flow rate, so Fig. 9 is simply a display of the fit. The paper's own caveats—'the parameters' combinations are not necessarily unique', 'the determined input parameters were mainly tailored to achieve a good match between measured and simulated O3 densities', and the statement that a Maxwellian vibrational distribution is 'unlikely to be the case in the experiment'—confirm that the agreement does not provide independent evidence for the vibrational mechanism. The tau_v trend (18 s at 0 slm to 35 s at high flow) also runs opposite to the paper's convective-removal argument, since shorter residence time would be expected to shorten, not lengthen, the rise time of vibrational excitation; this further weakens the physical interpretation, although it is an inconsistency rather than a circular step. Overall, the central claim that flow rate suppresses the O3-to-NOx transition through reduced nN2(v>12) reduces by construction to the fitted T0v/tau_v values, giving partial circularity.

Assumptions & free parameters 8 free parameters · 5 assumptions · 0 invented entities

The central claim rests on eight fitted parameters and several unverified modeling assumptions. In particular, the key explanatory variable, nN2(v>=12), is never measured; it is computed from fitted T0_v and tau_v values. No new physical entities are introduced.

free parameters (8)
  • n_O = 7.3e17 to 1.4e18 m^-3 (increasing with flow)
    Atomic oxygen density in the near-plasma zone; drives ozone formation, fitted to match measured O3 profiles.
  • T0_v = 6500 K at 0 slm descending to 4500 K at 8-10 slm
    Steady-state vibrational temperature of N2; controls nN2(v>=12) and the mode transition timing; fitted per flow rate.
  • tau_v = 18 s at 0 slm rising to 35 s at 8-10 slm
    Time constant for the rise of vibrational temperature; shifts the mode transition in time; fitted per flow rate.
  • T_g = 310 K
    Gas temperature far from plasma; affects O3 production and consumption rates; kept at room temperature.
  • T_p = 335 K to 340 K
    Gas temperature near plasma; affects the near-plasma chemistry; fitted.
  • n_O2(a1Delta) = 1e18 m^-3
    Fixed density of singlet oxygen; affects O3 consumption via R21; taken as a free constant based on prior models.
  • n_N2(A3Sigma) = 1e15 m^-3
    Fixed density of metastable nitrogen; affects O3 consumption and NO production; free constant from prior models.
  • r_N = 1e18 m^-3 s^-1
    Fixed production rate of atomic nitrogen (R17); estimated by comparison of measured and simulated densities.
assumptions (5)
  • domain assumption Maxwellian vibrational distribution function for N2(v>=12)
    Equation 4 assumes a Maxwellian form for the vibrational distribution; the text notes this is unlikely to hold experimentally, so T_v values are effective parameters.
  • domain assumption Homogeneous plasma layer with temporally constant O, N2(A3Sigma), and O2(a1Delta) densities and constant N production rate
    Section IV states the pulsed nature of the discharge is neglected and these quantities are effective spatial and temporal averages.
  • domain assumption O is confined to the near-plasma zone while N2(v) is uniformly distributed
    Section IV justifies this from lifetimes of the species, but it is not directly measured in the present experiments.
  • domain assumption Absorption at 193 nm is attributed to N2O5 plus O3, with N2O4 neglected
    Section III notes N2O4 and N2O5 absorption cannot be separated; literature values are cited to justify neglecting N2O4, but no in-situ measurement is provided.
  • domain assumption Literature rate coefficients are valid under the present SDBD conditions
    Table IV compiles rate coefficients from atmospheric chemistry and plasma literature, some estimated (footnotes b and c), without in-situ validation.

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Cite this review

Pith. "Pith review of Influence of gas flow rate on modes of reactive oxygen and nitrogen species in a grid-type surface dielectric barrier discharge." pith.science (2026). https://pith.science/paper/NGM7FCHZ

@misc{pith2026250204851,
  author       = {Pith},
  title        = {Pith review of: Influence of gas flow rate on modes of reactive oxygen and nitrogen species in a grid-type surface dielectric barrier discharge},
  year         = {2026},
  howpublished = {\url{https://pith.science/paper/NGM7FCHZ}},
  note         = {Machine review of arXiv:2502.04851}
}
read the original abstract

The presented work investigates a surface dielectric barrier discharge (SDBD) operated dry synthetic air as the working gas using a combination of experimental measurements and simulations. The primary objective is to characterize the production and consumption dynamics of reactive oxygen and nitrogen species to enhance the understanding of their formation and facilitate control of the discharge for applications. Densities of O3, NO2, and N2O5 are measured under varying gas flow rates, utilizing optical absorption spectroscopy as the diagnostic method. A semi-empirical chemical kinetics model is developed based on a compilation of reactions from previous studies on similar types of discharges. The results reveal two previously known and distinct operating modes, with a mode transition occurring between the modes as the flow rate is varied. The results indicate the dependency of the mode transition on the density of sufficiently vibrationally excited nitrogen molecules, which is represented in the model by an increased vibrational temperature at lower gas flow rates. Furthermore, key reactions responsible for the production and consumption of ozone and nitrogen oxides are identified, providing insight into the importance of macroscopic parameters, such as gas temperatures and different time constants, that influence the nonlinear balance of these reactions.

Figures

Figures reproduced from arXiv: 2502.04851 by the authors.

Figure 1
Figure 1. FIG. 1. Sketch of the electrode configuration used to ignite the [PITH_FULL_IMAGE:figures/full_fig_p002_1.png] view at source ↗
Figure 2
Figure 2. FIG. 2. Schematic drawing of the reactor chamber and periph [PITH_FULL_IMAGE:figures/full_fig_p003_2.png] view at source ↗
Figure 3
Figure 3. FIG. 3. Schematic of the optical absorption spectroscopy [PITH_FULL_IMAGE:figures/full_fig_p004_3.png] view at source ↗
Figures from the paper (6 more)
Figure 5
Figure 5. Figure 5: FIG. 5. Schematic drawing of the spatial assumptions consid [PITH_FULL_IMAGE:figures/full_fig_p004_5.png]
Figure 6
Figure 6. Figure 6: FIG. 6. Measured densities of a) O [PITH_FULL_IMAGE:figures/full_fig_p007_6.png]
Figure 9
Figure 9. Figure 9: FIG. 9. Exemplary simulated density profiles of N [PITH_FULL_IMAGE:figures/full_fig_p009_9.png]
Figure 10
Figure 10. Figure 10: compares the measured and simulated densities of O3 and NO2 for a flow rate of 0 slm. The results demonstrate a good qualitative agreement between the simulation and the measurements, with absolute 0 50 100 150 200 250 300 10 -4 10 -3 10 -2 10 -1 10 0 10 1 0 slm 2 slm…
Figure 11
Figure 11. Figure 11: FIG. 11. Comparison of simulated and measured densities of [PITH_FULL_IMAGE:figures/full_fig_p010_11.png]
Figure 12
Figure 12. Figure 12: FIG. 12. Comparison of simulated and measured densities of [PITH_FULL_IMAGE:figures/full_fig_p010_12.png]

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Works this paper leans on

42 extracted references · 39 canonical work pages

  1. [1]

    author author T. v. \ Woedtke , author M. Laroussi ,\ and\ author M. Gherardi ,\ title title Foundations of plasmas for medical applications , \ https://doi.org/10.1088/1361-6595/ac604f journal journal Plasma Sources Science and Technology \ volume 31 ,\ pages 054002 ( year 2022 ) NoStop

    work page doi:10.1088/1361-6595/ac604f

  2. [2]

    Sun , author Z

    author author J. Sun , author Z. Qu , author Y. Gao , author T. Li , author J. Hong , author T. Zhang , author R. Zhou , author D. Liu , author X. Tu , author G. Chen , author V. Brüser , author K.-D. \ Weltmann , author D. Mei , author Z. Fang , author A. Borras , author A. Barranco , author S. Xu , author C. Ma , author L. Dou , author S. Zhang , author...

    work page

  3. [3]

    author author M. C. \ Kim , author S. H. \ Yang , author J.-H. \ Boo ,\ and\ author J. G. \ Han ,\ title title Surface treatment of metals using an atmospheric pressure plasma jet and their surface characteristics , \ https://doi.org/https://doi.org/10.1016/S0257-8972(03)00560-7 journal journal Surface and Coatings Technology \ volume 174-175 ,\ pages 839...

    doi:10.1016/s0257-8972(03)00560-7

  4. [4]

    author author D. P. \ Subedi , author U. M. \ Joshi ,\ and\ author C. S. \ Wong ,\ title Dielectric Barrier Discharge (DBD) Plasmas and Their Applications , \ in\ https://doi.org/10.1007/978-981-10-4217-1_13 booktitle Plasma Science and Technology for Emerging Economies: An AAAPT Experience \ ( publisher Springer Singapore ,\ address Singapore ,\ year 201...

    work page doi:10.1007/978-981-10-4217-1_13

  5. [5]

    Schutze , author J

    author author A. Schutze , author J. Jeong , author S. Babayan , author J. Park , author G. Selwyn ,\ and\ author R. Hicks ,\ title title The atmospheric-pressure plasma jet: a review and comparison to other plasma sources , \ https://doi.org/10.1109/27.747887 journal journal IEEE Transactions on Plasma Science \ volume 26 ,\ pages 1685--1694 ( year 1998 ) NoStop

    work page doi:10.1109/27.747887

  6. [6]

    author author I. E. \ Kieft , author E. P. \ v. d. Laan ,\ and\ author E. Stoffels ,\ title title Electrical and optical characterization of the plasma needle , \ https://doi.org/10.1088/1367-2630/6/1/149 journal journal New Journal of Physics \ volume 6 ,\ pages 149 ( year 2004 ) NoStop

    work page doi:10.1088/1367-2630/6/1/149

  7. [7]

    Böddecker , author M

    author author A. Böddecker , author M. Passmann , author A. N. T. S. \ Segura , author A. Bodnar , author F. Awakowicz , author T. Oppotsch , author M. Muhler , author P. Awakowicz , author A. R. \ Gibson , author I. Korolov ,\ and\ author T. Mussenbrock ,\ title title The role of flow field dynamics in enhancing volatile organic compound conversion in a ...

    work page doi:10.1088/1361-6463/ad8454

  8. [8]

    Schücke , author J.-L

    author author L. Schücke , author J.-L. \ Gembus , author N. Peters , author F. Kogelheide , author R. T. \ Nguyen-Smith , author A. R. \ Gibson , author J. Schulze , author M. Muhler ,\ and\ author P. Awakowicz ,\ title title Conversion of volatile organic compounds in a twin surface dielectric barrier discharge , \ https://doi.org/10.1088/1361-6595/abae...

    work page doi:10.1088/1361-6595/abae0b

Show all 42 references
  1. [9]

    Schmidt , author M

    author author M. Schmidt , author M. Schiorlin ,\ and\ author R. Brandenburg ,\ title title Studies on the Electrical Behaviour and Removal of Toluene with a Dielectric Barrier Discharge , \ https://doi.org/doi:10.1515/chem-2015-0056 journal journal Open Chemistry \ volume 13 ...

    doi

  2. [10]

    Yang , author H.-J

    author author L. Yang , author H.-J. \ Yan , author X.-H. \ Qi , author S.-X. \ Zhao ,\ and\ author C.-S. \ Ren ,\ title title Geometry effects of sdbd actuator on atmospheric-pressure discharge plasma airflow acceleration , \ https://doi.org/10.1109/TPS.2015.2475360 journal j...

  3. [11]

    Zhu , author Y

    author author Y. Zhu , author Y. Wu , author W. Cui , author Y. Li ,\ and\ author M. Jia ,\ title title Modelling of plasma aerodynamic actuation driven by nanosecond SDBD discharge , \ https://doi.org/10.1088/0022-3727/46/35/355205 journal journal Journal of Physics D: Applie...

    doi

  4. [12]

    Šimek , author S

    author author M. Šimek , author S. Pekárek ,\ and\ author V. Prukner ,\ title title Ozone production using a power modulated surface dielectric barrier discharge in dry synthetic air , \ https://doi.org/10.1007/s11090-012-9382-z journal journal Plasma Chemistry and Plasma Proc...

    doi

  5. [13]

    author author R. G. \ Rice ,\ title title Applications of ozone for industrial wastewater treatment - a review , \ https://doi.org/10.1080/01919512.1997.10382859 journal journal Ozone: Science & Engineering \ volume 18 ,\ pages 477--515 ( year 1996 ) NoStop

    1997

  6. [14]

    Šírová , author M

    author author J. Šírová , author M. Sedlářová , author J. Piterková , author L. Luhová ,\ and\ author M. Petřivalský ,\ title title The role of nitric oxide in the germination of plant seeds and pollen , \ https://doi.org/https://doi.org/10.1016/j.plantsci.2011.03.014 journal ...

    doi

  7. [15]

    author author A. B. \ Shekhter , author V. A. \ Serezhenkov , author T. G. \ Rudenko , author A. V. \ Pekshev ,\ and\ author A. F. \ Vanin ,\ title title Beneficial effect of gaseous nitric oxide on the healing of skin wounds , \ https://doi.org/https://doi.org/10.1016/j.niox....

    doi

  8. [16]

    Shimizu , author Y

    author author T. Shimizu , author Y. Sakiyama , author D. B. \ Graves , author J. L. \ Zimmermann ,\ and\ author G. E. \ Morfill ,\ title title The dynamics of ozone generation and mode transition in air surface micro-discharge plasma at atmospheric pressure , \ https://doi.or...

    doi

  9. [17]

    author author M. J. \ Pavlovich , author D. S. \ Clark ,\ and\ author D. B. \ Graves ,\ title title Quantification of air plasma chemistry for surface disinfection , \ https://doi.org/10.1088/0963-0252/23/6/065036 journal journal Plasma Sources Science and Technology \ volume ...

    doi

  10. [18]

    Park , author W

    author author S. Park , author W. Choe ,\ and\ author C. Jo ,\ title title Interplay among ozone and nitrogen oxides in air plasmas: Rapid change in plasma chemistry , \ https://doi.org/https://doi.org/10.1016/j.cej.2018.07.039 journal journal Chemical Engineering Journal \ vo...

    2018 doi

  11. [19]

    Liu , author J

    author author K. Liu , author J. Zuo , author C. Ran , author M. Yang , author W. Geng , author S. Liu ,\ and\ author K. Ostrikov ,\ title title Reduced electric field and gas temperature effects on chemical product dynamics in air surface dielectric barrier discharges: from m...

    doi

  12. [20]

    Xi , author S

    author author W. Xi , author S. Luo , author D. Liu , author Z. Wang , author Z. Liu , author L. Guo , author X. Wang ,\ and\ author M. Rong ,\ title title The effect of humidity on the discharge mode transition of air discharge plasma , \ https://doi.org/10.1063/5.0107803 jou...

    doi

  13. [21]

    Zhu , author M

    author author Z. Zhu , author M. Zhang , author L. Wang , author J. Zhang , author S. Luo , author Z. Wang , author L. Guo , author Z. Liu , author D. Liu ,\ and\ author M. Rong ,\ title title Comparison of discharge mode transition of air plasma under pulsed and sinusoidal ex...

    doi

  14. [22]

    \ Huh , author J

    author author S.-C. \ Huh , author J. H. \ Bae , author H. Lee , author J. Kim , author W. Choe ,\ and\ author S. Park ,\ title title Individual quantification of ozone and reactive nitrogen species in mixtures by broadband UV –visible absorption spectra deconvolution , \ http...

    doi

  15. [23]

    Sun , author X

    author author Z. Sun , author X. Zheng , author H. Zheng , author Z. Zhao ,\ and\ author J. Li ,\ title title Effects of pulse rise time and pulse width on discharge mode transition of SDBD plasma under repetitive pulses , \ https://doi.org/10.1088/1361-6463/ad875d journal jou...

    doi

  16. [24]

    Böddecker , author A

    author author A. Böddecker , author A. Bodnar , author L. Schücke , author J. Giesekus , author K. Wenselau , author R. T. \ Nguyen-Smith , author T. Oppotsch , author C. Oberste-Beulmann , author M. Muhler , author A. R. \ Gibson ,\ and\ author P. Awakowicz ,\ title title A s...

    doi

  17. [25]

    Mohsenimehr \ and\ author A

    author author S. Mohsenimehr \ and\ author A. von Keudell ,\ title title Surface Dielectric Barrier Discharge (sDBD) for Flow Control in Plasma Conversion , \ https://doi.org/10.1007/s11090-023-10405-z journal journal Plasma Chemistry and Plasma Processing \ volume 43 ,\ pages...

    doi

  18. [26]

    Schücke , author A

    author author L. Schücke , author A. Bodnar , author N. Friedrichs , author A. Böddecker , author N. Peters , author K. Ollegott , author C. Oberste-Beulmann , author P. Wirth , author R. T. \ Nguyen-Smith , author I. Korolov , author A. R. \ Gibson , author M. Muhler ,\ and\ ...

    doi

  19. [27]

    Offerhaus , author J.-W

    author author B. Offerhaus , author J.-W. \ Lackmann , author F. Kogelheide , author V. Bracht , author R. Smith , author N. Bibinov , author K. Stapelmann ,\ and\ author P. Awakowicz ,\ title title Spatially resolved measurements of the physical plasma parameters and the chem...

    doi

  20. [28]

    Kogelheide , author B

    author author F. Kogelheide , author B. Offerhaus , author N. Bibinov , author P. Krajinski , author L. Schücke , author J. Schulze , author K. Stapelmann ,\ and\ author P. Awakowicz ,\ title title Characterisation of volume and surface dielectric barrier discharges in N 2 –O ...

    doi

  21. [29]

    author author B. Offerhaus ,\ title Characterisation of a novel twin surface dielectric barrier discharge designed for the purification of gas streams ,\ @noop type Doctoral thesis ,\ school Ruhr-Universität Bochum, Universitätsbibliothek ( year 2018 ) NoStop

    2018

  22. [30]

    Keller-Rudek , author G

    author author H. Keller-Rudek , author G. K. \ Moortgat , author R. Sander ,\ and\ author R. Sörensen ,\ title title The MPI-Mainz UV/VIS Spectral Atlas of Gaseous Molecules of Atmospheric Interest , \ https://doi.org/10.5194/essd-5-365-2013 journal journal Earth System Scienc...

    doi

  23. [31]

    Sakiyama , author D

    author author Y. Sakiyama , author D. B. \ Graves , author H.-W. \ Chang , author T. Shimizu ,\ and\ author G. E. \ Morfill ,\ title title Plasma chemistry model of surface microdischarge in humid air and dynamics of reactive neutral species , \ https://doi.org/10.1088/0022-37...

    doi

  24. [32]

    author author R. B. \ Bird , author W. E. \ Stewart ,\ and\ author E. N. \ Lightfoot ,\ @noop title Transport Phenomena \ ( publisher Wiley ,\ year 2002 ) NoStop

    2002

  25. [33]

    Böddecker , author M

    author author A. Böddecker , author M. Passmann , author S. Wilczek , author L. Schücke , author I. Korolov , author R. Skoda , author M. Mussenbrock , author A. R. \ Gibson ,\ and\ author P. Awakowicz ,\ title title Interactions between flow fields induced by surface dielectr...

    doi

  26. [34]

    Park , author J

    author author S. Park , author J. Kim , author H. Lee , author D. Han , author S. Park , author S. B. \ Kim ,\ and\ author W. Choe ,\ title title Nonheating ozone suppression in pulsed air discharges: role of pulse duration and repetition rate , \ https://doi.org/10.1088/1361-...

    doi

  27. [35]

    author author J. T. \ Herron \ and\ author D. S. \ Green ,\ title title Chemical Kinetics Database and Predictive Schemes for Nonthermal Humid Air Plasma Chemistry. Part II. Neutral Species Reactions , \ https://doi.org/https://doi.org/10.1023/A:1011082611822 journal journal P...

    doi

  28. [36]

    Atkinson , author D

    author author R. Atkinson , author D. L. \ Baulch , author R. A. \ Cox , author J. N. \ Crowley , author R. F. \ Hampson , author R. G. \ Hynes , author M. E. \ Jenkin , author M. J. \ Rossi ,\ and\ author J. Troe ,\ title title Evaluated kinetic and photochemical data for atm...

    doi

  29. [37]

    author author J. T. \ Herron ,\ title title Evaluated Chemical Kinetics Data for Reactions of N( 2 D), N( 2 P), and N 2 (A 3 _u^+ ) in the Gas Phase , \ https://doi.org/10.1063/1.556043 journal journal Journal of Physical and Chemical Reference Data \ volume 28 ,\ pages 1453--...

    doi

  30. [38]

    Capitelli , author C

    author author M. Capitelli , author C. M. \ Ferreira , author B. F. \ Gordiets ,\ and\ author A. I. \ Osipov ,\ @noop title Plasma Kinetics in Atmospheric Gases \ ( publisher Springer ,\ year 2000 ) NoStop

    2000

  31. [39]

    author author J. B. \ Burkholder , author J. P. D. \ Abbatt , author C. Cappa , author T. S. \ Dibble , author C. E. \ Kolb , author V. L. \ Orkin , author D. M. \ Wilmouth , author S. P. \ Sander , author S. P. \ Barker , author J. D. \ Crounse , author R. E. \ Huie , author ...

  32. [40]

    author author W. M. \ Jones \ and\ author N. Davidson ,\ title title The thermal decomposition of ozone in a shock tube , \ https://pubs.acs.org/doi/pdf/10.1021/ja00874a005 journal journal J. Am. Chem. Soc \ volume 84 ( year 1962 ) NoStop

    doi

  33. [41]

    Hjorth , author J

    author author J. Hjorth , author J. Notholt ,\ and\ author G. Restelli ,\ title title A spectroscopic study of the equilibrium NO 2 + NO 3 + M 2 N 2 O 5 + M and the kinetics of the O 3 /N 2 O 5 /NO 3 /NO 2 /air system , \ https://doi.org/https://doi.org/10.1002/kin.550240107 j...

    doi

  34. [42]

    author author H. S. \ Johnston , author C. A. \ Cantrell ,\ and\ author J. G. \ Calvert ,\ title title Unimolecular decomposition of NO 3 to form NO and O 2 and a review of N 2 O 5 /NO 3 kinetics , \ https://doi.org/https://doi.org/10.1029/JD091iD04p05159 journal journal Journ...

    doi

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Reviewed August 8, 2026 · model on record in the stance chip above.